Calcium Fluoride Window Polarization Control for ArF Laser

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Solution Overview

Problem

Existing semiconductor exposure apparatuses face challenges in maintaining a high degree of polarization of laser beams due to birefringence caused by mechanical and thermal stresses, leading to degradation and increased risk of window cleavage and damage, especially with ArF excimer lasers.

Innovation Solution

A degree of polarization control device using a calcium fluoride crystal substrate with surfaces parallel to the (111) crystal face, rotated around the [111] axis to control the Brewster angle, coupled with a polarization monitor and controller to adjust the rotation angle and maintain optimal polarization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional window is used in the laser chamber, then the structure is simple, but the window is susceptible to mechanical stress and gas pressure causing cleavage and damage

Engineering Contradiction:
Improvewindow resistance to mechanical stress and gas pressureVSAvoidwindow structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The window is constructed as a composite structure comprising a first window made of calcium fluoride crystal and a second window made of a different material, where the two windows are bonded together. This composite construction allows each window material to be optimized for specific functions: the calcium fluoride window resists ultraviolet laser irradiation and maintains polarization, while the second window provides mechanical strength to withstand gas pressure and thermal stress, thereby solving the contradiction between reliability and structural simplicity.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the laser beam passes through optical elements at arbitrary angles, then the system is easy to align, but birefringence degrades the degree of polarization

Engineering Contradiction:
Improvedegree of polarization maintenanceVSAvoidoptical alignment complexity
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent specifies that the laser beam must pass through the calcium fluoride crystal window at a particular angle (the Brewster angle) relative to the crystal's optical axis. By controlling this angular parameter, the birefringence effect is minimized, allowing the laser beam to maintain a high degree of polarization (90% or higher). The window is designed with specific crystal orientation and surface angles to achieve this optimal beam passage condition, resolving the contradiction between polarization maintenance and alignment ease.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If a single-material window is used, then the manufacturing is simple, but it cannot simultaneously resist ultraviolet laser irradiation and mechanical stress

Engineering Contradiction:
Improvecomprehensive resistance to UV laser and mechanical stressVSAvoidwindow manufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The window assembly uses a composite structure with a first window of calcium fluoride crystal optimized for ultraviolet laser resistance and polarization maintenance, and a second window of a different material optimized for mechanical strength and thermal stress resistance. The bonding interface between the two windows is designed to distribute mechanical loads effectively. This composite approach enables the system to simultaneously resist ultraviolet laser irradiation, mechanical stress, and thermal stress, overcoming the limitations of single-material windows while maintaining manufacturing feasibility through standardized bonding processes.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution reduces damage from mechanical and gas stresses, effectively controls the degree of polarization, and suppresses degradation from strong ultraviolet laser irradiation, enhancing the operational lifespan and performance of the apparatus.

Implementation Method 1

the Brewster angle being selected for the incident angle

Methodology Applied
Scientific EffectBrewster's angle: Brewster's Angle

Implementation Method 2

degradation and increased risk of window cleavage and damage, especially with ArF excimer lasers

Methodology Applied
Scientific EffectBirefringence: Birefringence

Data Source

PatentUS8902948B2Polarization purity control device and gas laser apparatus provided with the same
Publication Date: 2014.12.02 GIGAPHOTON INC
  • US8902948B2 patent drawing
  • US8902948B2 patent drawing
  • US8902948B2 patent drawing

AI summary

A degree of polarization control device includes:a calcium fluoride crystal substrate for transmitting a laser beam;a polarization monitor for measuring the degree of polarization of a laser beam transmitted through the calcium fluoride crystal substrate; anda controller for controlling the rotation angle of the calcium fluoride crystal substrate according to the degree of polarization measured by the polarization monitor;the calcium fluoride crystal substrate being formed by a flat plate having a laser beam entering surface and a laser beam exiting surface running in parallel with the (111) crystal face, the Brewster angle being selected for the incident angle, the rotation angle around the [111] axis operating as a central axis being controlled by the controller.