Calcium Hydrogen Carbonate Remineralization System

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Solution Overview

Problem

Current methods for remineralizing desalinated water, such as those using lime or limestone, are inefficient, require large equipment, and have environmental drawbacks, while existing installations for preparing calcium hydrogen carbonate solutions are time-dependent and require significant tank space.

Innovation Solution

A circular communication system comprising a dosing unit, multiple batch lines, and a membrane filtration unit, specifically a cross-flow membrane microfiltration or ultrafiltration device, for continuous preparation of a calcium hydrogen carbonate solution, which can be used for efficient remineralization of water.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional limestone bed filtration is used for remineralization, then water quality is improved, but the plant footprint becomes very large due to slow dissolution rate

Engineering Contradiction:
Improvewater qualityVSAvoidplant footprint
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The patent changes the physical-chemical parameters of calcium carbonate by using micronized particles (reducing particle size to micrometer range) and controlling pH through CO2 injection. This increases the dissolution rate and allows for a compact plant footprint while maintaining effective remineralization.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the large-scale mechanical limestone bed filtration system with a chemical dissolution system using micronized calcium carbonate suspended in water, accelerated by CO2 injection. This substitution enables much smaller equipment volume while achieving the same remineralization effect.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If lime process is used for remineralization, then water quality is improved, but carbon dioxide footprint increases significantly

Engineering Contradiction:
Improvewater qualityVSAvoidcarbon dioxide footprint
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent captures CO2 that would otherwise be a waste product or harmful emission and uses it as a reagent to accelerate calcium carbonate dissolution. This converts the harmful CO2 into a beneficial process input, reducing the overall carbon footprint while improving dissolution efficiency.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the chemical environment by injecting CO2 to lower pH, which increases the solubility and dissolution rate of calcium carbonate. This parameter change enables faster remineralization without requiring lime, thus reducing CO2 emissions associated with lime production.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If conventional batch preparation systems are used, then calcium hydrogen carbonate solution is produced, but significant tank space is required and the process is time-dependent

Engineering Contradiction:
Improvecalcium hydrogen carbonate solutionVSAvoidtank space
Core Design Contradiction:
Quantity of substanceVSVolume of stationary object

Solution Approach 1:

The patent implements a continuous flow system where water, micronized calcium carbonate, and CO2 are continuously mixed and reacted in a flow-through reactor. This eliminates the need for large batch tanks and allows continuous production of the remineralization solution, significantly reducing space requirements.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent divides the preparation process into sequential stages within a compact flow system: mixing of calcium carbonate suspension, CO2 injection for pH adjustment, and filtration. This segmentation allows each function to be performed in a small dedicated unit rather than requiring one large tank.

Inventive Principle:
Principle #1Segmentation

4Productivity

If rapid dissolution of calcium carbonate is achieved, then productivity is improved, but dissolution rate naturally remains slow without additional measures

Engineering Contradiction:
Improvedissolution rateVSAvoidcalcium carbonate dissolution
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent changes multiple parameters simultaneously: reduces particle size to micrometer range, increases surface area through suspension, and adjusts pH through CO2 injection. These parameter changes work together to dramatically accelerate the dissolution rate of calcium carbonate without requiring additional chemical additives.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses CO2 gas injection (pneumatics) to acidify the water and enhance calcium carbonate dissolution. The gas-liquid-solid interaction creates a highly efficient dissolution process that is much faster than conventional water-only dissolution of limestone.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables efficient, economic, and ecological remineralization of water with a smaller plant footprint, producing a solution of calcium hydrogen carbonate suitable for desalinated or naturally soft water sources, improving water quality and reducing environmental impact.

Implementation Method 1

at least one membrane filtration unit provided with at least one inlet and at least one outlet, wherein the at least one membrane filtration unit is a cross flow membrane microfiltration device and/or a cross flow ultrafiltration device

Methodology Applied
Scientific EffectMicrofiltration: Filter (physical)

Implementation Method 2

at least one membrane filtration unit provided with at least one inlet and at least one outlet, wherein the at least one membrane filtration unit is a cross flow membrane microfiltration device and/or a cross flow ultrafiltration device

Methodology Applied
Scientific EffectUltrafiltration: Filter (physical)

Implementation Method 3

passing the soft water through a bed of granular limestone dissolving the calcium carbonate in the water flow

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 4

a carbon dioxide absorption process of excessively supplying carbon dioxide into the desalinated water to absorb the carbon dioxide

Methodology Applied
Scientific EffectCarbon dioxide absorption: Absorption (physical)

Data Source

PatentEP2805923B1Installation for the preparation of a solution of calcium hydrogen carbonate suitable for the remineralization of water
Publication Date: 2018.10.31 OMYA INT AG
  • EP2805923B1 patent drawingFigure 1
  • EP2805923B1 patent drawingFigure 2
  • EP2805923B1 patent drawing

AI summary

The invention relates to an installation for the preparation of a solution of calcium hydrogen carbonate and the use of such an installation for the continuous preparation of a solution of calcium hydrogen carbonate as well as the use of such an installation for the remineralization of water.