Calcium Hypochlorite Composition with Transient Color Indicator

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Calcium hypochlorite treatments in recreational water systems lack visual feedback for end-users to confirm effective dispersion, as calcium hypochlorite is colorless when dissolved in water, making it difficult to ascertain biocidal activity.

Innovation Solution

A water treatment composition containing calcium hypochlorite and an oxidizable pigment or dye, which provides a transient color when dissolved, serving as a visual cue for biocidal activity, and is coated with a water-soluble material to prevent premature bleaching, with the composition being free of surfactants to avoid foaming.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of information

If calcium hypochlorite is used as a treatment for recreational water systems, then biocidal activity is provided, but visual feedback for confirming effective dispersion is lacking because calcium hypochlorite is colorless when dissolved in water

Engineering Contradiction:
Improvevisual feedbackVSAvoidconfirmation of biocidal activity
Core Design Contradiction:
Loss of informationVSReliability

Solution Approach 1:

The patent applies color changes by incorporating an oxidizable dye into the calcium hypochlorite composition. The dye remains intact during storage but oxidizes and changes color when contacted by water, providing visual feedback that the composition has been effectively dispersed and is providing biocidal activity. This resolves the contradiction by adding visual information without compromising the biocidal function.

Inventive Principle:
Principle #32Color changes

2Loss of information

If a transient color indicator is added to provide visual feedback, then visual signal of biocidal activity is provided, but premature bleaching may occur before the composition is administered to the water

Engineering Contradiction:
Improvevisual signalVSAvoidcolor stability
Core Design Contradiction:
Loss of informationVSStability of the object's composition

Solution Approach 1:

The patent applies preliminary action by coating the oxidizable dye particles with a water-soluble material before administration. This coating protects the dye from premature oxidation and bleaching during storage and handling. When the composition is administered to water, the coating dissolves first, allowing the dye to then oxidize and provide the visual signal. This resolves the contradiction by maintaining color stability until the moment of use.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If surfactants are added to the composition, then dispersion efficacy may be improved, but foaming of the recreational water occurs

Engineering Contradiction:
Improvedispersion efficacyVSAvoidfoaming
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent applies the taking out principle by removing surfactants from the composition formulation. Instead of using surfactants to improve dispersion, the patent relies on the natural dissolution properties of the water-soluble coating material and the mechanical action of water circulation to disperse the composition. This resolves the contradiction by eliminating the harmful foaming effect while maintaining adequate dispersion efficacy through alternative mechanisms.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The transient color indicator provides a visual signal of biocidal activity, ensuring effective dispersion of calcium hypochlorite, allowing end-users to confirm treatment efficacy without altering the water's hue, and preventing foaming in recreational water systems.

Implementation Method 1

The other chamber contains a dye solution bleachable via oxidation from a colored state to a colorless state

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

The oxidizable pigment and/or the oxidizable dye particles may be provided with a water soluble coating

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentEP3247678B1Methods of using calcium hypochlorite compositions with transient color indicators
Publication Date: 2022.03.16 INNOVATIVE WATER CARE LLC

AI summary

A water treatment composition for treating a body of water is provided that provides visual feedback to the end-user of the effectiveness of the composition. The composition contains a majority of calcium hypochlorite particles; and an effective amount of colored particles containing an oxidizable pigment oxidizable dye and a water soluble material. The colored particles release the oxidizable dye to the body of the water to provide a transient color to the recreational water during dissolution of the composition in the body of water, the transient color providing a visual cue to the end-user signaling of the biocidal activity of the composition. Also provided is a method of applying the water treatment composition to recreational water.