Calcium Phosphate Bone Adhesive for Moist Fracture Fixation

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Solution Overview

Problem

Current metallic osteosynthesis materials for bone fixation are unsuitable for comminuted fractures, intra-articular fractures, and pediatric fractures due to interference with joint function and bone growth, and lack of adhesion in moist physiological environments, with no commercially available alternatives to metallic osteosynthesis materials.

Innovation Solution

An adhesive composition comprising tetracalcium phosphate, phosphorylated serine, and polydopamine, which forms a biocompatible and adhesive bone glue with enhanced osteoinductive properties, allowing for rapid bone fixation and integration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If metallic osteosynthesis materials are used for bone fixation, then mechanical strength and stability are improved, but adhesion in moist physiological environment deteriorates and complications associated with metallic implants occur

Engineering Contradiction:
Improvemechanical strengthVSAvoidadhesion in moist physiological environment
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention uses a composite material system consisting of calcium phosphate ceramic particles embedded in a phosphorylated serine matrix, creating a bioinspired adhesive that combines the mechanical properties of ceramic with the adhesive properties of the organic polymer, enabling strong bonding in moist physiological environments

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If metallic osteosynthesis materials are used for bone fixation, then mechanical stability is improved, but biocompatibility and absence of complications deteriorate

Engineering Contradiction:
Improvemechanical stabilityVSAvoidcomplications associated with metallic implants
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The invention changes the material parameters from metallic to biocompatible organic-inorganic composite, specifically using phosphorylated serine and calcium phosphate ceramic which are naturally compatible with bone tissue, eliminating issues of infection, allergic reactions, and mechanical complications associated with metal implants

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If calcium phosphate ceramics are used for bone fixation, then biocompatibility is improved, but adhesion to bone tissue deteriorates

Engineering Contradiction:
ImprovebiocompatibilityVSAvoidadhesion to bone tissue
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The invention creates a composite where calcium phosphate ceramic particles provide biocompatibility and osteoconductivity while the phosphorylated serine matrix provides adhesive properties, combining both functions in a single material system that bonds strongly to bone tissue

Inventive Principle:
Principle #40Composite materials

4Strength

If metallic hardware is used for fracture fixation, then structural support is improved, but suitability for comminuted and pediatric fractures deteriorates

Engineering Contradiction:
Improvestructural supportVSAvoidsuitability for comminuted and pediatric fractures
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The invention changes from rigid metallic hardware to a flexible adhesive material that can adapt to irregular fracture geometries, small fragment sizes in comminuted fractures, and growing bones in pediatric patients, providing structural support through bonding rather than mechanical fixation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive composition provides strong and biocompatible bone fixation, promoting bone growth and integration, while avoiding complications associated with metallic implants, suitable for a wide range of fracture types including comminuted and pediatric fractures.

Implementation Method 1

phosphorylated serine can be added to a phosphocalcic ceramic to obtain adhesive properties

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

an adhesive composition comprising tetracalcium phosphate, phosphorylated serine and polydopamine

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP4448030B1Bone adhesive composition
Publication Date: 2025.09.03 INSERM (INST NAT DE LA SANTEET DE LA RECHERCHE MEDICALE)
  • EP4448030B1 patent drawingFigure 1~2
  • EP4448030B1 patent drawingFigure 3

AI summary

The present invention relates to an adhesive composition comprising a calcium phosphate ceramic selected from tetracalcium phosphate and alpha-tricalcium phosphate, phosphorylated serine, polydopamine, and an aqueous solvent. The invention also relates to a kit, to a method for producing said adhesive composition as well as to the uses thereof.