Candle Wax Polymer Anti-Crystallization

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Solution Overview

Problem

Candle wax produced from fatty acids derived from animal or plant sources tends to crystallize during solidification, leading to an aesthetically undesirable rough surface, and the use of paraffin wax to prevent crystallization is costly and requires large quantities.

Innovation Solution

A candle wax composition incorporating a polymer with specific units that hinder the orderly arrangement of long fatty acid chains, preventing crystallization and resulting in a smooth surface, achieved by mixing a candle wax base with a random copolymer having specific formulae that reduce crystallization without the need for significant amounts of additives.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If paraffin is added to prevent crystallization, then the surface smoothness is improved, but the manufacturing cost increases

Engineering Contradiction:
Improvesurface smoothnessVSAvoidmanufacturing cost
Core Design Contradiction:
ShapeVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameters by using fatty acid esters with specific chain lengths (C16-C22) and specific molecular weight ranges (500-5000 g/mol). These parameter changes allow the ester to interfere with crystal formation at much lower concentrations (0.1-5% by weight) compared to paraffin, thereby maintaining surface smoothness while reducing manufacturing cost

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a cost-effective alternative to expensive paraffin by using fatty acid esters that can be derived from renewable resources. These esters provide the necessary anti-crystallization effect at low concentrations, making the overall formulation more economical while achieving the desired surface quality

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Shape

If paraffin is added to prevent crystallization, then the surface smoothness is improved, but the quantity of additive required increases

Engineering Contradiction:
Improvesurface smoothnessVSAvoidquantity of additive
Core Design Contradiction:
ShapeVSQuantity of substance

Solution Approach 1:

The patent achieves superior anti-crystallization efficiency by carefully selecting esters with optimal molecular parameters - specifically those with alkyl chains of C16-C22 and molecular weights of 500-5000 g/mol. These parameter-optimized esters disrupt crystal formation at concentrations as low as 0.1-5% by weight, dramatically reducing the quantity of additive needed compared to conventional paraffin formulations

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If vegetable lipid-based wax is used, then the environmental sustainability is improved, but the crystallization during solidification occurs

Engineering Contradiction:
Improveenvironmental sustainabilityVSAvoidcrystallization resistance
Core Design Contradiction:
Object-generated harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces fatty acid esters as intermediary substances that mediate between the environmentally beneficial vegetable lipid base and the desired anti-crystallization performance. These esters act as molecular spacers that prevent fatty acid chains from organizing into crystals, thereby maintaining both the environmental sustainability of the lipid base and the stability of the wax composition during solidification

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite wax system combining vegetable lipid-based candle wax with fatty acid esters. This composite formulation leverages the renewable, environmentally friendly properties of the lipid base while the ester component provides anti-crystallization functionality, achieving both sustainability and compositional stability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer addition effectively minimizes crystallization, rendering the candle wax smooth and aesthetically pleasing, with visible crystals eliminated, and allows for a cost-effective and efficient production process.

Implementation Method 1

The polymer comprises units having the formula (I) wherein Z is a C10-C40 saturated alkyl group... The polymer according to the invention hinders long fatty acid chains from neatly arranging themselves next to each other, so that a disorderly arrangement results.

Methodology Applied
Scientific EffectSteric hindrance:

Implementation Method 2

Candle wax is either made from a range of waxy substances derived from insects, or it is produced from fatty acids derived from animal fats and plant oils... the candle wax can crystallise during solidification

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentEP2776545B1Candle wax comprising a polymer and method for making candle wax
Publication Date: 2017.10.11 N CHEM
  • EP2776545B1 patent drawingFigure 1~1B
  • EP2776545B1 patent drawing
  • EP2776545B1 patent drawing

AI summary

This invention pertains to candle wax and a method for making candle wax. The candle wax comprises a candle wax base mixture and a polymer wherein the polymer comprises units of the formula (I) wherein X is an alkyl, alkenyl, alkyl maleic anhydride or alkylene-imine; Y is selected from the group consisting of -O-, -S-, -NH-, -NCH2-, -NCH2CH2-,-COO- of which either the carbon or the oxygen group is bound to X, -C(=O)NH, trialkoxysilane, preferably trimethoxysilane or triethoxysilane, benzyl, amide group; Z is H or a C1 - C40 alkyl group or a C1 - C40 alkenyl group; n is a positive integer, preferably is n>3; if Y is -COO-, then the polymer is a copolymer comprising at least two different units, and if Z is H or a methyl or ethyl, than the polymer is a copolymer comprising at least one unit comprising a C3-C40 alkyl group or C3-C40 alkenyl group.