Capacitive Humidity Sensor with Nanoporous Hydrophilic Dielectric

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Solution Overview

Problem

Existing humidity sensors lack sensitivity for detecting low levels of humidity below 55% RH, particularly below 20% RH, and often require complex setups or suffer from high hysteresis and temperature dependence.

Innovation Solution

A capacitive humidity sensor utilizing a nanoporous dielectric material with pores less than 2 nm in radius, treated to enhance hydrophilicity, is used between electrodes, along with a floating permeable electrode to improve sensitivity and accuracy at low humidity levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional dielectric materials are used in capacitive humidity sensors, then the sensor structure is simple, but the sensitivity for detecting low humidity levels below 55% RH is insufficient

Engineering Contradiction:
Improvehumidity detection sensitivityVSAvoidsensor structure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs a nanoporous dielectric material with controlled pore sizes (5-50 nm) to enhance humidity sensing capability. The porous structure provides increased surface area and capillary action that facilitates water vapor adsorption even at low humidity levels, thereby improving measurement precision without requiring complex sensor architectures

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention uses composite dielectric materials combining organic and inorganic components, such as silane-modified polymers mixed with metal oxides (TiO2, SiO2). This composite approach creates materials with optimized hydrophilicity and pore structure that enhance sensitivity to low humidity while maintaining structural simplicity

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If the dielectric material is made more hydrophilic to improve low humidity detection, then sensitivity increases, but hysteresis and temperature dependence worsen

Engineering Contradiction:
Improvelow humidity detection sensitivityVSAvoidhysteresis and temperature stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent optimizes the pore size parameter of the dielectric material to fall within 5-50 nm, which balances hydrophilicity for enhanced sensitivity with sufficient structural stability to minimize hysteresis. The controlled pore dimensions prevent excessive water retention that would cause hysteresis while maintaining adequate adsorption capacity for low humidity detection

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces hydrophilic functional groups (such as silanol groups) specifically at the pore surfaces and interfaces of the dielectric material, rather than uniformly throughout the bulk material. This localized hydrophilicity enhancement improves sensitivity to water vapor while the bulk material maintains its thermal and structural stability, reducing temperature dependence and hysteresis

Inventive Principle:
Principle #3Local quality

3Measurement precision

If nanoporous dielectric material with pores less than 2 nm is used, then sensitivity for low humidity measurement is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvemoisture detection sensitivityVSAvoidpore size control precision
Core Design Contradiction:
Measurement precisionVSManufacturing precision

Solution Approach 1:

The patent employs preliminary chemical treatments and surface modifications during the dielectric material fabrication process to pre-establish the desired pore structure and hydrophilic properties. By incorporating pore-forming agents and performing controlled annealing or plasma treatments during manufacturing, the nanoporous structure with 5-50 nm pores is created with sufficient precision without requiring post-fabrication nanopore formation techniques

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sensor achieves high sensitivity for low humidity measurements, allowing for precise detection of small moisture amounts, reducing hysteresis, and maintaining stability across a wide temperature range, making it suitable for applications in encapsulated components like integrated circuits and MEMS/NEMS.

Implementation Method 1

When the humidity varies, the quantity of water absorbed by said layer of dielectric material also varies, which leads to a modification of the dielectric constant of this layer

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

The nano-porous material comprises hydrophilic sites. The nano-porous material has undergone a treatment to make it hydrophilic or more hydrophilic

Methodology Applied
Scientific EffectHydrophilic interaction: Hydrophile

Implementation Method 3

In a sensor of the capacitive type, the electrodes of the capacitor can for example be in the form of combs... forms a capacitor. When the humidity varies, the quantity of water absorbed by said layer of dielectric material also varies, which leads to a modification of the dielectric constant of this layer, and a variation of the capacitance of the capacitor

Methodology Applied
Scientific EffectCapacitance: Capacitance

Data Source

PatentEP2304416B1Capacitive humidity sensor with nanoporous hydrophilic dielectric and fabrication process therefor
Publication Date: 2019.09.11 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP2304416B1 patent drawingFigure 1A~1B
  • EP2304416B1 patent drawingFigure 2A~2B
  • EP2304416B1 patent drawingFigure 3A~3B

AI summary

The invention relates to a humidity detector of the capacitive type, that comprises at least one nanoporous dielectric material provided between at least a first electrode of a capacitor and at least a second electrode of the capacitor, to a humidity detection or measuring device including such a detector, and to a method for making such a detector.