Aluminum Electrolytic Capacitor Aging for Stable Oxide and Low Leakage

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Solution Overview

Problem

Aluminum electrolytic capacitors in implantable cardioverter defibrillators require frequent maintenance due to dielectric relaxation and electrolyte loss, leading to reduced energy density and shortened battery life.

Innovation Solution

A two-step aging process for aluminum electrolytic capacitors involving impregnation with different electrolytes and controlled voltage and temperature conditions to grow a stable oxide layer, reducing the need for maintenance and extending battery life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If aluminum electrolytic capacitors are stored at room temperature without charging, then capacitor deformation occurs due to dielectric relaxation and electrolyte loss, but frequent maintenance charge cycles are required which shorten battery life

Engineering Contradiction:
Improvecapacitor stabilityVSAvoidbattery life
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The capacitor undergoes an aging process before implantation that pre-grows the oxide layer and stabilizes the dielectric structure. This preliminary action reduces subsequent deformation and maintenance needs during the device's operational life, thereby extending battery life while maintaining reliability

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If a single aging process is used, then the oxide layer grows but electrolyte is lost due to hydrogen evolution, requiring re-impregnation which increases process complexity

Engineering Contradiction:
Improveoxide layer qualityVSAvoidaging process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The aging process is divided into two distinct stages: a first aging process that grows the oxide layer, followed by a second aging process that stabilizes the structure without significant electrolyte loss. This segmentation allows each stage to be optimized independently, achieving high oxide layer quality while minimizing the need for re-impregnation and reducing overall process complexity

Inventive Principle:
Principle #1Segmentation

3Volume of stationary object

If capacitor volume is minimized for high energy density, then fewer anodes can be used, but this reduces capacitance and energy storage capacity

Engineering Contradiction:
Improvecapacitor volumeVSAvoidcapacitance
Core Design Contradiction:
Volume of stationary objectVSQuantity of substance

Solution Approach 1:

Multiple anodes are nested within a compact stack configuration, with each anode surrounded by cathode and separator layers in a space-efficient arrangement. This nested structure maximizes the number of anodes that can fit within the minimal capacitor volume, thereby achieving both high energy density and sufficient capacitance for ICD applications

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method extends the maintenance cycle of aluminum electrolytic capacitors to up to 5 years in storage and 2 years post-implantation, significantly increasing the battery life of implantable cardioverter defibrillators by minimizing deformation and leakage current.

Implementation Method 1

impregnating an aluminum electrolytic capacitor with a first electrolyte to form a first impregnated capacitor

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

aging the first impregnated capacitor using a first aging process to form a first aged capacitor

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

aging the first impregnated capacitor using a first aging process

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Data Source

PatentUS11894199B2Method of aging an aluminum electrolytic capacitor
Publication Date: 2024.02.06 PACESETTER INC
  • US11894199B2 patent drawing
  • US11894199B2 patent drawing
  • US11894199B2 patent drawing

AI summary

A method of manufacturing an aluminum electrolytic capacitor includes impregnating an aluminum electrolytic capacitor with a first electrolyte to form a first impregnated capacitor, aging the first impregnated capacitor using a first aging process to form a first aged capacitor, impregnating the first aged capacitor with a second electrolyte to form a second impregnated capacitor, the second electrolyte being different from the first electrolyte, aging the second impregnated capacitor using a final aging process to form a final aged capacitor, and impregnating the final aged capacitor with a third electrolyte.