Solid electrolytic capacitor including a valve metal support and a cathode

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Solution Overview

Problem

Conventional solid electrolytic capacitors face challenges in moisture resistance and equivalent series resistance (ESR), particularly when used in vehicles, necessitating improvements in these areas.

Innovation Solution

A solid electrolytic capacitor design featuring a cathode part with a solid electrolyte layer, an intermediate layer containing a conductive material and catalytic metal, and a metal plating layer on the surface, which enhances moisture resistance and reduces ESR by using a conductive polymer and palladium-based materials for electroless plating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a silver paste layer is used as the outermost layer of the cathode part, then the capacitor can be manufactured with conventional processes, but the moisture resistance is insufficient and ESR is high

Engineering Contradiction:
Improvemoisture resistanceVSAvoidcathode structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The cathode part is segmented into three distinct layers: solid electrolyte layer, intermediate layer, and metal plating layer. This segmentation allows each layer to perform its specific function - the intermediate layer provides moisture barrier and catalytic activity, while the metal plating layer provides conductivity, thereby resolving the contradiction between moisture resistance and manufacturing complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The intermediate layer uses a composite material containing both conductive material (for electrical connection) and catalytic metal (for plating reaction and moisture resistance). This composite structure enables simultaneous achievement of moisture resistance and electrical conductivity without requiring complex multi-step manufacturing processes

Inventive Principle:
Principle #40Composite materials

2Reliability

If a silver paste layer is used as the outermost layer, then the manufacturing process is simple, but the equivalent series resistance is high

Engineering Contradiction:
Improveelectrical conductivityVSAvoidcathode layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention changes the material parameter of the outermost layer from silver paste to metal plating (such as copper or aluminum). This parameter change significantly improves electrical conductivity and reduces ESR, while the intermediate layer maintains the necessary catalytic and conductive properties to support this change without requiring excessive structural complexity

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the cathode part lacks an intermediate layer with catalytic metal, then the manufacturing process is simpler, but the metal plating layer cannot be formed and moisture resistance is poor

Engineering Contradiction:
Improvewater resistanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The intermediate layer is designed with multi-functionality: it provides electrical conductivity through conductive material, moisture barrier through water-resistant properties, and catalytic activity through embedded catalytic metal particles. This consolidation of multiple functions into a single layer simplifies the overall manufacturing process while achieving superior moisture resistance

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The design improves moisture resistance and reduces ESR, ensuring better performance in harsh environments by utilizing a conductive and water-resistant structure with a copper plating layer.

Implementation Method 1

A catalytic metal having catalytic activity for plating is provided on the surface of the intermediate layer

Methodology Applied
Scientific EffectElectroless plating: Catalysis

Data Source

PatentUS12505958B2Solid electrolytic capacitor including a valve metal support and a cathode
Publication Date: 2025.12.23 TDK CORP
  • US12505958B2 patent drawing
  • US12505958B2 patent drawing
  • US12505958B2 patent drawing

AI summary

A solid electrolytic capacitor includes: a valve metal support having an anode terminal region and a cathode forming region and forming an anode part; and a cathode part provided in a cathode forming region of the valve metal support. The cathode part includes: a solid electrolyte layer that is disposed on a surface of a dielectric layer provided at least on the cathode forming region of the valve metal support and contains a conductive polymer; a waterproof seed layer that is disposed on a surface of the solid electrolyte layer and contains a conductive material; and a metal plating layer disposed on a surface of the waterproof seed layer. A catalytic metal having catalytic activity for plating is provided on the surface of the waterproof seed layer.