Solid Electrolytic Capacitor External Coating Adhesion

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Solution Overview

Problem

Conventional solid electrolytic capacitors face challenges in achieving good mechanical robustness and electrical performance due to difficulties in forming a thick solid electrolyte layer with effective adhesion and mechanical robustness of the polymeric outer layer.

Innovation Solution

A solid electrolytic capacitor design featuring a conductive polymer layer sandwiched between a carbonaceous and metal layer in the external coating, enhancing mechanical robustness and electrical performance by preventing delamination and improving adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a polymeric outer layer is applied to cover the solid electrolyte surface, then mechanical robustness is improved, but adhesion to the graphite/silver layer deteriorates

Engineering Contradiction:
Improvemechanical robustnessVSAvoidadhesion
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent introduces a separate adhesion layer positioned between the polymeric outer layer and the graphite/silver layer. This intermediary layer serves as a mediator that provides both mechanical support and strong bonding interfaces to both adjacent layers, thereby maintaining mechanical robustness while solving the adhesion problem.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs a composite structure consisting of multiple materials with different functions: a polymeric outer layer for mechanical protection, a specially formulated adhesion layer for bonding, and the underlying graphite/silver layer for electrical termination. This composite approach allows each layer to optimize its specific function without compromising the overall structure.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If sequential dipping into separate solutions is used to form the conductive polymer electrolyte, then manufacturing flexibility is improved, but achieving thick solid electrolyte layer deteriorates

Engineering Contradiction:
Improvemanufacturing flexibilityVSAvoidsolid electrolyte thickness
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The patent combines multiple dipping steps into a unified multi-layer formation process where each dip deposits a specific functional layer. By merging the formation of the conductive polymer electrolyte with the subsequent adhesion and outer layers in a coordinated sequence, the process achieves both manufacturing flexibility and sufficient electrolyte thickness.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent transitions from a single-layer thick electrolyte approach to a multi-layered structure where thickness is achieved through stacking multiple functional layers in the vertical dimension. This allows the solid electrolyte to achieve sufficient total thickness while maintaining manufacturing flexibility through sequential processing.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Strength

If the solid electrolyte layer is made thicker to improve mechanical robustness, then mechanical strength is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvemechanical robustnessVSAvoidmanufacturing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent segments the solid electrolyte structure into multiple distinct layers, each with specific thickness and function. Rather than forming one thick layer, the structure divides the total thickness into several thinner functional layers (conductive polymer electrolyte layer, adhesion layer, polymeric outer layer), which simplifies the manufacturing process for each individual layer while achieving the required total thickness.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed design increases mechanical robustness and electrical performance by reducing delamination risks and enhancing adhesion, leading to improved capacitor reliability and efficiency.

Implementation Method 1

The external coating further contains a second conductive polymer layer that is positioned between the carbonaceous layer and the metal layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

The external coating contains a carbonaceous layer and a metal layer that overlies the carbonaceous layer. The external coating further contains a second conductive polymer layer that is positioned between the carbonaceous layer and the metal layer

Methodology Applied
Scientific EffectLamination: Lamination

Data Source

PatentUS8125768B2External coating for a solid electrolytic capacitor
Publication Date: 2012.02.28 KYOCERA AVX COMPONENTS CORP
  • US8125768B2 patent drawing
  • US8125768B2 patent drawing
  • US8125768B2 patent drawing

AI summary

A solid electrolytic capacitor that includes an anode body, a dielectric overlying the anode body, a solid electrolyte that contains one or more conductive polymers and overlies the dielectric, and an external coating that overlies the solid electrolyte, is provided. The external coating includes at least one carbonaceous layer (e.g., graphite) and at least one metal layer (e.g., silver). In addition to the aforementioned layers, the external coating also includes at least one conductive polymer layer that is disposed between the carbonaceous and metal layers. Among other things, such a conductive polymer layer can reduce the likelihood that the carbonaceous layer will delaminate from the solid electrolyte during use. This can increase the mechanical robustness of the part and improve its electrical performance.