Solid Electrolytic Capacitor Conductive Bridge Polymerization

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Solution Overview

Problem

The manufacturing of solid electrolytic capacitors with intrinsically conducting polymeric cathodes faces challenges due to high costs and variability in polymer coverage, as well as physical damage risks from external connections, which affect the dielectric properties and polymer quality.

Innovation Solution

A method is developed to form a conductive polymeric coating by creating a conductive bridge between a conductive seed layer and an external electrical contact, allowing electrochemical polymerization without direct physical contact, thus reducing manufacturing costs and preventing damage to the dielectric and anode layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an external electrical contact is placed in direct physical contact with the conductive seed layer, then electrical connection is achieved, but physical damage to the dielectric and polymeric cathode layer occurs

Engineering Contradiction:
Improveelectrical connection reliabilityVSAvoidphysical damage to dielectric and cathode layer
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A conductive bridge layer is introduced as an intermediary between the external electrical contact and the conductive seed layer. This bridge layer serves as a mediator that enables electrical connection while preventing direct physical contact that would cause damage to the dielectric and cathode layer. The bridge layer is specifically designed to be compatible with the dielectric material.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The electrical connection path is segmented into multiple distinct layers: the external electrical contact, the conductive bridge layer, and the conductive seed layer. This segmentation allows each layer to perform its specific function without direct contact between incompatible components, thereby preventing damage while maintaining electrical connectivity.

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If repetitive dip/dry cycles are used for chemical in-situ polymerization, then sufficient polymer coverage is achieved, but manufacturing cost increases

Engineering Contradiction:
Improvepolymer coverage uniformityVSAvoidmanufacturing efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The conductive bridge layer is formed in advance before the polymerization process. This preliminary action provides a stable conductive foundation that enables more efficient polymerization, reducing the number of repetitive dip/dry cycles needed to achieve sufficient and uniform polymer coverage.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The introduction of the conductive bridge layer changes the electrical and chemical parameters of the substrate, creating more favorable conditions for polymerization. This parameter change allows for reduced processing cycles while maintaining or improving polymer coverage quality.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If current manufacturing methods with direct physical contact are used, then external electrical connection is achieved, but equipment complexity and manufacturing cost increase

Engineering Contradiction:
Improveelectrical connection capabilityVSAvoidhardware complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The conductive bridge layer acts as an intermediary that simplifies the overall device structure by eliminating the need for complex external connection hardware. The bridge layer provides a straightforward integration path between the external contact and the active cathode region, reducing equipment complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enhances the efficiency of capacitor formation by maintaining polymer quality and dielectric integrity, reducing manufacturing costs, and improving the reliability of solid electrolytic capacitors.

Implementation Method 1

electrochemically polymerizing a monomer thereby forming an electrically conducting polymer of monomer on the conductive seed layer

Methodology Applied
Scientific EffectElectrochemical polymerization:

Data Source

PatentUS9847179B2Solid electrolytic capacitor and method of manufacturing a solid electrolytic capacitor
Publication Date: 2017.12.19 KEMET ELECTRONICS CORP
  • US9847179B2 patent drawing
  • US9847179B2 patent drawing
  • US9847179B2 patent drawing

AI summary

Provided is a method for forming a capacitor. The method includes:providing an anode with a dielectric thereon and a conductive node in electrical contact with the anode;applying a conductive seed layer on the dielectric;forming a conductive bridge between the conductive seed layer and the conductive node;applying voltage to the anode;electrochemically polymerizing a monomer thereby forming an electrically conducting polymer of monomer on the conductive seed layer; anddisrupting the conductive bridge between the conductive seed layer and the conductive node.