Capacitor Lower Electrode Doping for Higher Capacitance Scaling

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Solution Overview

Problem

As semiconductor devices integrate, the reduced area of capacitors leads to decreased capacitance, necessitating a higher dielectric constant in the dielectric layer to maintain capacitance.

Innovation Solution

Incorporating a doped region in the lower electrode of the capacitor, which affects the crystal phase of the dielectric layer, thereby increasing its dielectric constant and capacitance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the area of the capacitor is reduced to increase integration degree, then the device density is improved, but the capacitance is reduced

Engineering Contradiction:
Improveintegration degreeVSAvoidcapacitance
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent changes the chemical composition parameter of the lower electrode by introducing a doped region with different stoichiometry (e.g., metal nitride with varying nitrogen content or metal oxide with varying oxygen content). This parameter change in the electrode material induces a corresponding change in the dielectric layer's crystal phase and dielectric constant, thereby maintaining capacitance despite area reduction

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a doped region with localized different properties within the lower electrode structure. This local quality change (different composition or doping concentration in specific regions of the electrode) creates a non-uniform interface with the dielectric layer, promoting favorable crystal phase formation locally and enhancing overall capacitance

Inventive Principle:
Principle #3Local quality

2Productivity

If the area of the capacitor is reduced to increase integration degree, then the device density is improved, but the dielectric constant must be increased to maintain capacitance

Engineering Contradiction:
Improveintegration degreeVSAvoiddielectric constant
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent systematically changes the compositional parameters of the lower electrode (such as metal to ligand ratio in metal nitrides or metal oxides) to induce phase transitions or stabilize high-dielectric-constant crystal phases in the dielectric layer. By controlling electrode composition parameters, the dielectric constant is enhanced without requiring larger capacitor area

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures where the lower electrode consists of multiple materials or phases (e.g., metal nitride with dopants, or composite of metal oxide and conductive material). This composite structure interacts with the dielectric layer to stabilize desirable crystal phases and achieve higher effective dielectric constant

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The doped region in the lower electrode enhances the dielectric constant of the dielectric layer, resulting in a capacitor with greater capacitance compared to one without the doped region.

Implementation Method 1

the doped region of the lower electrode is configured to increase a capacitance of the capacitor... Incorporating a doped region in the lower electrode of the capacitor, which affects the crystal phase of the dielectric layer

Methodology Applied
Scientific EffectCrystal phase change: Phase Change

Implementation Method 2

The capacitor may include two electrodes and a dielectric layer between the two electrodes. Capacitance may be proportionate to an area of the capacitor and a dielectric constant of the dielectric layer

Methodology Applied
Scientific EffectCapacitance: Capacitance

Data Source

PatentUS12356642B2Semiconductor devices including capacitor and methods of manufacturing the semiconductor devices
Publication Date: 2025.07.08 SAMSUNG ELECTRONICS CO LTD
  • US12356642B2 patent drawing
  • US12356642B2 patent drawing
  • US12356642B2 patent drawing

AI summary

Semiconductor devices including a capacitor and methods of forming the same are provided. The semiconductor devices may include a capacitor that include a lower electrode, an upper electrode on the lower electrode, and a dielectric layer extending between the lower electrode and the upper electrode. The lower electrode may include a doped region that contacts the dielectric layer, and the doped region of the lower electrode is configured to increase a capacitance of the capacitor.