Electrolytic Capacitor Electrolyte for Low-Scintillation High Voltage

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

High voltage electrolytic capacitors used in implantable cardioverter defibrillators face challenges in minimizing size while maintaining high energy density and efficiency, as conventional capacitors require large components and are prone to scintillations at higher voltages, leading to energy loss and reduced delivered-to-store ratio.

Innovation Solution

A method for manufacturing electrolytic capacitors involving the formation of an ester material from glycol and acids, followed by quenching and addition of ammonium-based materials, results in an electrolytic material with optimized conductivity and reduced scintillation rates, achieving a high delivered-to-store ratio and improved voltage withstand.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If higher conductivity electrolytes are used to improve delivered-to-store ratio, then discharge efficiency is improved, but scintillations occur that damage the oxide and lead to energy loss

Engineering Contradiction:
Improvedelivered-to-store ratioVSAvoidoxide damage from scintillations
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the electrolyte by using a carboxylic acid salt (such as lithium acetate, lithium propionate, or lithium butyrate) instead of traditional electrolytes. This parameter change allows the electrolyte to maintain high conductivity for efficient energy delivery while suppressing scintillation damage to the oxide layer, thereby resolving the contradiction between energy efficiency and reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite electrolyte system combining carboxylic acid salts with specific solvents (cyclic carbonates like EC, PC, or GC). This composite material approach achieves both high conductivity and low scintillation rates by leveraging the synergistic effects of the salt and solvent components, simultaneously improving delivered-to-store ratio and protecting the oxide layer.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If the working voltage is increased to reduce capacitor size, then energy density is improved, but scintillations increase causing energy loss

Engineering Contradiction:
Improveenergy densityVSAvoidenergy loss from scintillations
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent changes the electrolyte composition parameters by introducing carboxylic acid salts with specific molecular structures (acetate, propionate, butyrate). These parameter changes enable the electrolyte to withstand higher working voltages (900V-1000V) without generating scintillations, thus achieving high energy density while maintaining low energy loss.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If conventional high voltage capacitors are used to achieve 80J energy output, then required energy is delivered, but device size becomes 60-70 cc

Engineering Contradiction:
Improveenergy outputVSAvoiddevice size
Core Design Contradiction:
Use of energy by moving objectVSVolume of stationary object

Solution Approach 1:

The patent changes multiple parameters including electrolyte composition (carboxylic acid salt concentration), solvent type (cyclic carbonate selection), and operating voltage (900V-1000V). These parameter changes enable the capacitor to achieve 80J energy output with significantly reduced volume, shrinking the device from conventional 60-70 cc to a more compact size suitable for implantable applications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process yields capacitors with a high delivered-to-store ratio, reduced scintillation rates, and increased voltage withstand, enabling smaller, more efficient energy storage for implantable cardioverter defibrillators while maintaining battery life and reducing size requirements.

Implementation Method 1

quenching the ester material for a determined period

Methodology Applied
Scientific EffectQuenching: Heat Treatment

Implementation Method 2

the electrolyte that is used for the ionic mobility of the charge through from the anode to the cathode

Methodology Applied
Scientific EffectIonic mobility: Electrolyte

Implementation Method 3

Aluminum electrolytic capacitors energy density is directly related to the surface area of the anodes generated in the electrochemical etching processes

Methodology Applied
Scientific EffectElectrochemical etching: Electrolysis

Data Source

PatentUS11763997B2Electrolytic capacitor
Publication Date: 2023.09.19 PACESETTER INC
  • US11763997B2 patent drawing
  • US11763997B2 patent drawing
  • US11763997B2 patent drawing

AI summary

A method is provided for manufacturing an electrolytic capacitor for an implantable cardioverter defibrillator. The method includes forming an ester material by adding at least one acid to a glycol, and quenching the ester material for a determined period. The method also includes adding an ammonium based material to the ester material after the ester material is quenched, and adding an additional acid after adding the ammonium based material to form an electrolytic material for the electrolytic capacitor.