Electrolytic Capacitor Electrode Foil With P-C Underlayer for Low Leakage

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Solution Overview

Problem

Existing electrolytic capacitors face increased leakage current when the metal element in the dielectric layer differs from the metal in the anode body, limiting capacitance and performance.

Innovation Solution

An electrode foil with a porous anode body and a dielectric layer containing an oxide of a second metal, where the underlayer includes phosphorus and carbon, is used, allowing for a gas phase method to form the dielectric layer and reduce leakage current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a dielectric layer containing an oxide of a second metal different from the first metal in the anode body is formed, then capacitance is improved, but leakage current increases

Engineering Contradiction:
ImprovecapacitanceVSAvoidleakage current
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

An underlayer containing phosphorus and carbon is introduced as an intermediary between the first metal framework and the second metal oxide dielectric layer. This underlayer acts as a mediator that enables the formation of a dielectric layer with different metal composition while preventing excessive leakage current, thus resolving the contradiction between achieving high capacitance and maintaining low leakage current.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs a composite structure consisting of the first metal framework, the phosphorus-carbon-containing underlayer, and the second metal oxide dielectric layer. This composite material approach allows combining the high capacitance benefits of different metal oxides while using the underlayer to suppress leakage current, achieving both improved capacitance and controlled leakage.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If an underlayer containing phosphorus and carbon is formed between the metal framework and the dielectric layer, then leakage current is reduced, but manufacturing complexity increases

Engineering Contradiction:
Improveleakage currentVSAvoidmanufacturing complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The underlayer containing phosphorus and carbon is formed as a preliminary step before depositing the second metal oxide dielectric layer. By preparing this underlayer in advance, the subsequent dielectric layer formation is facilitated, and the overall manufacturing process becomes more controlled, justifying the additional step through improved product performance.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces traditional chemical conversion treatment methods with a gas phase deposition method for forming the dielectric layer on the phosphorus-carbon underlayer. This substitution enables better control over the dielectric layer formation process and reduces leakage current while maintaining manufacturing feasibility.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If a gas phase method is used to form the dielectric layer, then manufacturing precision is improved, but production time increases

Engineering Contradiction:
Improvedielectric layer uniformityVSAvoidproduction time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The gas phase deposition process allows precise control of deposition parameters such as temperature, pressure, and gas flow rates to achieve uniform dielectric layer formation. By optimizing these parameters, high manufacturing precision is achieved while minimizing unnecessary process time, balancing quality and productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively reduces leakage current and enhances capacitance by stabilizing the surface and promoting uniform growth of the dielectric layer, improving acid resistance and overall performance.

Implementation Method 1

forming an underlayer on a surface of a metal framework consisting the porous part by heating the anode body to which the alkali solution adheres

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

forming, on a surface of the underlayer, a dielectric layer including a first layer containing an oxide of a second metal by a gas phase method

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS11848163B2Electrode foil for electrolytic capacitor, electrolytic capacitor, and method for manufacturing same
Publication Date: 2023.12.19 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US11848163B2 patent drawing
  • US11848163B2 patent drawing
  • US11848163B2 patent drawing

AI summary

An electrode foil for an electrolytic capacitor includes an anode body foil having a porous part, and a dielectric layer covering a surface of a metal framework constituting the porous part. The dielectric layer includes a first layer containing an oxide of a second metal, the second metal being different from a first metal contained in the metal framework. An underlayer that is continuous with the first layer is provided between the metal framework and the first layer. The underlayer contains phosphorus and carbon.