Electrolytic Capacitor Foil Coating for Low-ESR Polymer Adhesion

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Solution Overview

Problem

The increasing demand for higher voltage alternators in mild hybrid systems requires electrolytic capacitors with reduced equivalent series resistance (ESR) to manage higher ripple currents, but existing methods struggle to adequately adhere a sufficient amount of conductive polymer to the capacitor elements.

Innovation Solution

A method involving the application of a conductive polymer dispersion onto an electrode foil using a coating method, followed by partial removal of the dispersion medium, to form a conductive polymer layer that covers at least 90% of the foil's surface, enhancing the adhesion and reducing ESR.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If the amount of conductive polymer is increased to reduce ESR, then the ESR decreases, but it becomes difficult to allow a sufficient amount of conductive polymer to adhere onto the capacitor element

Engineering Contradiction:
ImproveESRVSAvoidamount of conductive polymer
Core Design Contradiction:
Loss of energyVSQuantity of substance

Solution Approach 1:

The conductive polymer layer is divided into multiple layers (first conductive polymer layer and second conductive polymer layer) with different components and functions. The first layer provides base adhesion and conductivity, while the second layer enhances conductivity and reduces ESR, allowing each layer to be optimized independently for both adhesion and low ESR performance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the conductive polymer layer have different properties - the first layer contains specific components for adhesion, while the second layer contains different components optimized for conductivity. This local differentiation allows the structure to simultaneously achieve good adhesion and low ESR

Inventive Principle:
Principle #3Local quality

2Area of stationary object

If a coating method is used to apply conductive polymer dispersion, then the coverage area increases, but the adhesion of conductive polymer to the electrode foil surface becomes challenging

Engineering Contradiction:
Improvecoverage areaVSAvoidadhesion
Core Design Contradiction:
Area of stationary objectVSStrength

Solution Approach 1:

The electrode foil surface undergoes preliminary treatment (etching and/or roughening) before applying the conductive polymer dispersion. This preliminary action creates a textured surface that mechanically interlocks with the polymer layer, significantly improving adhesion while maintaining wide coverage

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The conductive polymer layer is formulated as a composite material containing the conductive polymer component and a dispersant component. This composite structure improves both the coating processability for wide coverage and the adhesion to the electrode surface

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for a substantial increase in the amount of conductive polymer on the capacitor element, resulting in a capacitor with lower ESR and improved heat resistance, suitable for high ripple current applications, while also reducing impurities and enhancing withstand voltage.

Implementation Method 1

forming a first conductive polymer layer containing the first conductive polymer component, by applying the first conductive polymer dispersion to a surface of the electrode foil by a coating method

Methodology Applied
Scientific EffectCoating: Coatings

Implementation Method 2

at least partially removing the first dispersion medium

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS12176157B2Electrolytic capacitor and method for producing the same
Publication Date: 2024.12.24 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US12176157B2 patent drawing
  • US12176157B2 patent drawing
  • US12176157B2 patent drawing

AI summary

A method for producing an electrolytic capacitor, the method including steps of: preparing an electrode foil; preparing a first conductive polymer dispersion containing a first conductive polymer component and a first dispersion medium; forming a first conductive polymer layer containing the first conductive polymer component, by applying the first conductive polymer dispersion to a surface of the electrode foil by a coating method, and then at least partially removing the first dispersion medium; and fabricating a capacitor element, using the electrode foil having the first conductive polymer layer.