Capacitor Interlayer Materials for Low Leakage at High Integration

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Solution Overview

Problem

As semiconductor elements become more highly integrated and finer, they face challenges with decreased capacitance and increased leakage current, particularly due to structural deterioration and crystalline changes at the electrode-dielectric interface, which existing methods struggle to address effectively.

Innovation Solution

Incorporating a Group 13 element other than aluminum, such as boron, gallium, or indium, in the interlayer between the electrode and dielectric layers to enhance structural stability and reduce leakage current, while maintaining high capacitance, by using materials like gallium oxide or indium oxide with specific work functions and thicknesses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the size of capacitor is decreased for higher integration, then the capacitance decreases and leakage current increases

Engineering Contradiction:
Improveintegration densityVSAvoidcapacitance and leakage current
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the material parameter of the interlayer from conventional materials (such as titanium oxide or nickel oxide) to a material containing a Group 13 element other than aluminum (such as gallium oxide or indium oxide). This material parameter change modifies the work function and electronic structure of the interlayer, thereby reducing electron injection into the dielectric layer and suppressing leakage current, while maintaining structural stability at reduced capacitor dimensions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite structure where the interlayer is formed by combining a base material with a Group 13 element (other than aluminum) such as gallium or indium. This composite material approach creates an interlayer with optimized properties: the Group 13 element contributes specific electronic characteristics that reduce leakage, while the overall composite structure maintains mechanical and structural stability in the miniaturized capacitor geometry.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional interlayer materials are used, then manufacturing is simpler, but structural deterioration and crystalline changes occur at the electrode-dielectric interface

Engineering Contradiction:
Improveinterlayer fabricationVSAvoidinterface structural stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent modifies the chemical composition parameter of the interlayer by incorporating a Group 13 element (other than aluminum) such as gallium or indium. This compositional change results in an interlayer with enhanced structural stability and appropriate work function, preventing crystalline changes and structural deterioration at the electrode-dielectric interface while remaining compatible with existing manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in capacitors with improved structural stability, higher capacitance, and lower leakage current characteristics, effectively addressing the limitations of smaller semiconductor elements.

Implementation Method 1

the capacity of a capacitor is maintained by changing a capacitor structure, for example, by enlarging an electrode area or reducing the thickness of a dielectric layer

Methodology Applied
Scientific EffectElectron injection suppression:

Implementation Method 2

the interlayer includes a first interface material, and the first interface material includes at least one Group 13 element other than aluminum (Al)

Methodology Applied
Scientific EffectWork function effect:

Data Source

PatentUS20240234492A1Capacitor and device including the same
Publication Date: 2024.07.11 SAMSUNG ELECTRONICS CO LTD
  • US20240234492A1 patent drawing
  • US20240234492A1 patent drawing
  • US20240234492A1 patent drawing

AI summary

Provided are a capacitor and an electronic device including the same. The capacitor includes a first electrode layer, a second electrode layer, a dielectric layer disposed between the first electrode layer and the second electrode layer, and an interlayer disposed between the first electrode layer and the dielectric layer. The interlayer includes a first interface material, the first interface material includes at least one Group 13 element, and the at least one Group 13 element is not aluminum (Al).