Capacitor Manufacturing Using Conductive Polymer Solution

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Solution Overview

Problem

Existing capacitor manufacturing methods using π-conjugated conductive polymers face challenges with low conductivity, high leakage current, and poor productivity due to complex processes and inefficient polymerization methods.

Innovation Solution

A capacitor design incorporating a valve metal anode, oxidized dielectric layer, and a solid electrolyte layer containing a π-conjugated conductive polymer and polyanion, with a direct current voltage applied between the anode and cathode, and a resin component to reduce leakage current, enhancing conductivity and production efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If electrolytic polymerization method is used to form solid electrolyte layer, then a conductive polymer layer can be formed, but the process becomes extremely complex and requires pre-forming manganese oxide layer which has poor conductivity

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidprocess complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the complex electrolytic polymerization process and the pre-required manganese oxide layer formation step. Instead, it directly applies a conductive polymer solution containing π-conjugated conductive polymer and polyanion to the dielectric layer surface, followed by simple heating treatment, thereby removing the disturbing complex steps while achieving the desired conductive electrolyte layer.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces the complex, multi-step electrolytic polymerization process with a simple, direct coating method using a pre-prepared conductive polymer solution. This disposable-like approach applies the conductive polymer directly from solution without requiring complex in-situ polymerization equipment or pre-formed manganese oxide layers, significantly simplifying the manufacturing process.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Manufacturing precision

If chemical oxidative polymerization is performed repeatedly to ensure sufficient film thickness, then a satisfactory electrolyte layer can be formed, but the polymerization time becomes very long and production efficiency is poor

Engineering Contradiction:
Improveelectrolyte layer thicknessVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The invention performs preliminary action by pre-forming the conductive polymer and polyanion in a solution state before application. This allows the electrolyte layer to be deposited in a single coating step with sufficient thickness, eliminating the need for repeated polymerization cycles and significantly improving production efficiency while maintaining manufacturing precision.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution results in a capacitor with high conductivity and minimal leakage current, achieved through improved manufacturing processes that increase productivity and capacitance while reducing equivalent series resistance (ESR).

Implementation Method 1

an electrolytic oxidation step of forming a dielectric layer by electrolytically oxidizing the surface of an anode composed of a valve metal

Methodology Applied
Scientific EffectElectrolytic oxidation: Electrolysis

Implementation Method 2

an application step of performing a treatment in which a direct current voltage is applied between the anode and the cathode

Methodology Applied
Scientific EffectDirect current voltage treatment: Electrical Accumulator

Data Source

PatentUS8422202B2Capacitor and method for manufacturing the same
Publication Date: 2013.04.16 SHIN ETSU POLYMER CO LTD
  • US8422202B2 patent drawing
  • US8422202B2 patent drawing

AI summary

A method for manufacturing a capacitor that enables a capacitor having a high degree of conductivity and minimal leakage current to be obtained with a high level of productivity. A method for manufacturing a capacitor (10) according to the present invention includes an electrolytic oxidation step of forming a dielectric layer (12) by electrolytically oxidizing the surface of an anode (11) composed of a valve metal, a cathode positioning step of positioning a cathode (13) composed of a conductor in an opposing arrangement on the surface of the dielectric layer (12), a solid electrolyte formation step of forming a solid electrolyte layer (14) between the dielectric layer (12) and the cathode (13) using a conductive polymer solution containing a π-conjugated conductive polymer and a polyanion, and an application step of performing a treatment in which a direct current voltage is applied between the anode (11) and the cathode (13).