Carbazole Compound Material for High-Resolution Imaging Sensors
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Photoelectric conversion devices for imaging applications face challenges in achieving higher sensitivity and resolution, particularly in digital cameras, smartphones, and monitoring cameras, due to limitations in the utilization efficiency of incident light and resolution with conventional inorganic semiconductor-based devices.
Innovation Solution
A photoelectric conversion device material comprising a specific carbazole compound with optimized energy levels and mobility characteristics is used, which facilitates efficient hole and electron transport, reducing leakage current and enhancing contrast ratio.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Ease of manufacture
If inorganic semiconductor-based photoelectric conversion devices are used with RGB color filters disposed on a plane, then the device structure is simple and manufacturing is easier, but the utilization efficiency of incident light is low and resolution is limited
Solution Approach 1:
The patent transitions from planar color filter arrangement to a three-dimensional stacked architecture where multiple photoelectric conversion layers with different color sensitivities are stacked vertically. This dimensional change allows multiple color channels to occupy the same pixel footprint, thereby improving resolution without complicating the manufacturing process, as each layer can be independently optimized and deposited using standard semiconductor fabrication techniques.
Solution Approach 2:
The patent employs composite material structures combining inorganic semiconductor layers with organic semiconductor layers in a stacked configuration. The inorganic semiconductor provides high quantum efficiency and stable performance, while the organic semiconductor layers enable wavelength-selective absorption. This composite approach achieves both high resolution through vertical stacking and maintains manufacturing feasibility through established material deposition processes.
2Device complexity
If inorganic semiconductor-based photoelectric conversion devices use planar RGB color filters, then the device structure is simpler, but the utilization efficiency of incident light is reduced
Solution Approach 1:
The patent resolves the contradiction by moving from two-dimensional planar color filter arrangement to three-dimensional stacked photoelectric conversion layers. Each layer is optimized for specific wavelength regions, enabling simultaneous capture of multiple color channels within the same pixel area. This vertical stacking increases light utilization efficiency without proportionally increasing device complexity, as each layer can be independently designed and fabricated using standard semiconductor processing.
Solution Approach 2:
The patent segments the photoelectric conversion function across multiple thin layers, each responsible for detecting specific wavelength ranges. This segmentation allows specialized materials to be used in each layer for optimal wavelength selectivity, thereby improving overall light utilization efficiency while keeping individual layer complexity manageable through modular design.
3Productivity
If bias voltage is applied between electrodes to accelerate charge separation, then photoelectric conversion efficiency is improved, but leakage current from electrodes increases
Solution Approach 1:
The patent introduces organic semiconductor layers as intermediary materials between the inorganic semiconductor photoelectric conversion layers and the electrodes. These organic layers serve as charge transport mediators that facilitate efficient charge extraction while blocking harmful leakage currents. The organic semiconductors are specifically designed with appropriate energy levels and charge mobility to enable efficient operation under bias voltage while suppressing dark current, thus resolving the contradiction between conversion efficiency and leakage current.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The carbazole compound-based material enables a photoelectric conversion device with low dark current and high contrast ratio, improving the sensitivity and resolution of imaging devices.
Implementation Method 1
light having a desired wavelength is absorbed in the photoelectric conversion layer to generate an exciton, and then charge separation of the exciton generates a hole and an electron
Implementation Method 2
The P-type organic semiconductor is used as a hole transport material, and the N-type organic semiconductor is used as an electron transport material
Data Source
AI summary
Provided are a material that achieves higher sensitivity and higher resolution of a photoelectric conversion device for imaging, and a photoelectric conversion device for imaging using the above material. A material for a photoelectric conversion device for imaging includes a biscarbazole compound represented by Cz-(Ar)m-Cz. Cz represents a carbazolyl group, Ar independently represents an aromatic hydrocarbon group having 6 to 30 carbon atoms, and “m” represents an integer of 3 to 6. At least one Ar represents a divalent aromatic hydrocarbon group generated from naphthalene, phenanthrene, pyrene, or benzene.


