Carbazole-Based Compound for OLED Efficiency and Voltage Reduction

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Solution Overview

Problem

Current organic light emitting devices face challenges in achieving enhanced efficiency, low driving voltage, and extended lifetime due to limitations in material performance, particularly in the organic material layers.

Innovation Solution

A carbazole-based compound is introduced, which can be used in the organic material layers of the device, forming a multilayer structure that includes a hole injection layer, a hole transfer layer, an electron blocking layer, a light emitting layer, and an electron injection layer, improving the efficiency and stability of the device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in the organic material layer, then the device structure is simple, but the efficiency is low and the lifetime is short

Engineering Contradiction:
Improvedevice efficiencyVSAvoidmaterial layer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs composite organic material layers comprising multiple distinct organic materials with different functions (hole injection material, hole transfer material, electron transfer material, electron injection material). This composite structure enables simultaneous optimization of charge injection, transport, and recombination processes, thereby achieving enhanced device efficiency and lifetime without excessive structural complexity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The organic material layer is segmented into multiple functional sub-layers, each responsible for specific charge carrier operations. This segmentation allows independent optimization of each layer's material properties to maximize overall device performance while maintaining a systematic and manageable structure

Inventive Principle:
Principle #1Segmentation

2Power

If conventional organic materials are used, then the manufacturing process is simple, but the driving voltage is high

Engineering Contradiction:
Improvedriving voltageVSAvoidmanufacturing process complexity
Core Design Contradiction:
PowerVSEase of manufacture

Solution Approach 1:

The patent systematically adjusts key material parameters including HOMO/LUMO energy levels, charge carrier mobility, and layer thicknesses to optimize driving voltage. By carefully selecting materials with appropriate energy level alignments and optimizing layer thickness parameters, the device achieves reduced driving voltage while maintaining a manufacturable process

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional organic materials are used, then the device structure is straightforward, but the stability is poor

Engineering Contradiction:
Improvedevice stabilityVSAvoidorganic material layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent utilizes composite organic material layers with carefully selected materials that exhibit complementary properties for enhanced stability. The combination of different organic materials with distinct functional roles (hole injection, hole transfer, electron transfer, electron injection) creates a synergistic effect that improves overall device stability and reliability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces intermediate organic material layers that facilitate smooth charge carrier transitions between different functional regions. These intermediary layers act as buffers that reduce stress concentrations and improve interfacial stability, thereby enhancing overall device reliability

Inventive Principle:
Principle #24Intermediary (Mediator)

4Productivity

If conventional organic materials are used, then the material layer is simple, but the charge carrier balance is poor

Engineering Contradiction:
Improvecharge carrier balanceVSAvoidmaterial layer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent segments the organic material layer into four distinct functional layers, each optimized for specific charge carrier operations. This segmentation enables independent control and optimization of hole and electron injection, transport, and recombination processes, achieving superior charge carrier balance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each organic material layer is designed with locally optimized properties tailored to its specific function. The hole injection layer, hole transfer layer, electron transfer layer, and electron injection layer each have customized material compositions and thicknesses that maximize their respective charge carrier handling capabilities, resulting in overall charge balance optimization

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbazole-based compound enhances the efficiency and reduces the driving voltage of the organic light emitting device while extending its lifetime by effectively balancing electron and hole migration and improving the stability of the organic material layers.

Implementation Method 1

When a voltage is applied between the two electrodes in such an organic light emitting device structure, holes and electrons are injected to the organic material layer from the anode and the cathode, respectively

Methodology Applied
Scientific EffectCharge carrier injection and transport: Conduction (electrical)

Implementation Method 2

An organic light emission phenomenon generally refers to a phenomenon converting electrical energy to light energy using an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11950505B2Carbazole-based compound and organic light emitting diode comprising same
Publication Date: 2024.04.02 LG CHEM LTD
  • US11950505B2 patent drawing
  • US11950505B2 patent drawing
  • US11950505B2 patent drawing

AI summary

Provided is a compound of Chemical Formula 1:wherein:X1 is N or CR, X2 is N or CR′, and X3 is N or CR″;two or more of X1 to X3 are N;R, R′, R″ and R1 each independently is hydrogen or deuterium, a is an integer of 0 to 9, and when a is 2 or greater, the R1s are the same as or different from each other;Ar1 and Ar2 each independently is a substituted or unsubstituted aryl group;L is a direct bond or a substituted or unsubstituted arylene group, n is an integer of 1 to 3, and when n is 2 or 3, the Ls are the same as or different from each other; andR11 to R18 each independently is hydrogen, deuterium, a nitrile group, or a substituted or unsubstituted: alkyl group, cycloalkyl group, alkoxy group, aryloxy group, aryl group, or heteroaryl group, or bond to adjacent groups to form a substituted or unsubstituted ring,and an organic light emitting device comprising same.