Carbene Derivative Nanoparticle Synthesis Control

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Solution Overview

Problem

Current methods for synthesizing nanoparticles lack effective control over size, shape, and uniformity, limiting their application in devices that rely on precise quantum confinement effects.

Innovation Solution

A method involving the use of carbene derivatives as precursors in a wet chemistry process, where these derivatives are added to an organic solvent with metal precursors to grow nanoparticles, allowing for controlled reaction rates and resulting in nanoparticles with uniform size, shape, and structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional precursors are used in wet chemistry synthesis, then the synthesis process is simple and low cost, but the size, shape, structure and uniformity of nanoparticles cannot be efficiently controlled

Engineering Contradiction:
Improvecontrol over size, shape, structure and uniformity of nanoparticlesVSAvoidsimplicity and cost of synthesis process
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameters of the precursor by using carbene derivatives with specific molecular structures (Formulae 1 and 2) instead of conventional precursors. This parameter change in precursor chemistry enables efficient control over nanoparticle size, shape, structure and uniformity while maintaining the wet chemistry synthesis approach

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The carbene derivative acts as an intermediary species that mediates between the metal precursor and the growing nanoparticle. The carbene ligand coordinates to metal ions and controls their assembly and reduction, thereby mediating the formation process to achieve precise control over nanoparticle characteristics

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If vapor deposition processes (MOCVD, MBE) are used to prepare nanoparticles, then precise control over nanoparticle properties can be achieved, but the process complexity and cost increase significantly

Engineering Contradiction:
Improvecontrol over nanoparticle propertiesVSAvoidcomplexity of deposition process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical/physical vapor deposition processes (MOCVD, MBE) with a wet chemistry approach using carbene derivatives. This substitution maintains control over nanoparticle properties through chemical mechanisms rather than physical deposition, thereby reducing process complexity

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the fundamental parameter of synthesis methodology from vapor-phase physical deposition to solution-phase chemical synthesis. This parameter change enables achieving similar control over nanoparticle properties through a simpler, lower-cost wet chemistry process using carbene derivative precursors

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of nanoparticles with consistent dimensions and shapes, enhancing their properties and performance in devices by retarding the release rate of Group XVI elements, thus improving their electrical, optical, and mechanical properties.

Implementation Method 1

carbene derivatives represented by the following Formula 1 or 2 is used as one of the precursor: adding one or more precursors with one or more metal precursors to an organic solvent to grow a crystal

Methodology Applied
Scientific EffectChemical coordination: Chemical Bonding

Data Source

PatentUS8057780B2Method for preparing nanoparticles using carbene derivatives
Publication Date: 2011.11.15 SAMSUNG ELECTRONICS CO LTD
  • US8057780B2 patent drawing
  • US8057780B2 patent drawing
  • US8057780B2 patent drawing

AI summary

Disclosed herein is a method for synthesizing a nanoparticle using a carbene derivative. More specifically, provided is a method for synthesizing a nanoparticle by adding one or more precursors to an organic solvent to grow a crystal, wherein a specific carbene derivative is used as the precursor.