Carbon Aerogel Precursor via Binder Phase Conversion

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Solution Overview

Problem

Conventional carbon aerogels require precise adjustment of carbon material length and diameter, leading to high preparation costs and suboptimal conductivity and pore characteristics, limiting their commercialization and effective use as electrodes.

Innovation Solution

A method for preparing a carbon aerogel precursor involving mixing a carbon material with a dispersant and solvent, adjusting concentration, and using a binder to form a gelated solution, which can be converted into a carbon aerogel with high specific surface area and conductivity without adjusting the carbon material's physical properties, allowing for phase conversion and diverse formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the length and diameter of carbon material are finely adjusted to prepare carbon aerogel, then the pore structure and conductivity can be optimized, but the preparation cost increases significantly

Engineering Contradiction:
Improveelectrode performanceVSAvoidpreparation cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention extracts the critical dimension adjustment step from the preparation process. By using a binder that enables phase conversion, the method eliminates the need for precise carbon material dimension control while maintaining electrode performance through the binder's structural role during carbonization

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the key parameter from carbon material dimensions to binder properties (phase conversion capability and low carbonization ratio). This parameter shift allows preparation of high-performance carbon aerogels using carbon materials with unadjusted physical properties, significantly reducing preparation costs

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional organic aerogel is carbonized to prepare carbon aerogel, then the carbon aerogel can be obtained, but the conductivity and pore characteristics are insufficient

Engineering Contradiction:
Improveconductivity and pore characteristicsVSAvoidaerogel structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The binder serves as an intermediary substance that facilitates phase conversion and maintains the aerogel structure during carbonization. With a low carbonization ratio of 5-40%, the binder preserves pore characteristics while enabling the formation of a conductive carbon network, improving both conductivity and pore structure

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite system comprising carbon material and binder that work synergistically. The binder's phase conversion capability and low carbonization ratio enable the formation of a composite structure that maintains excellent pore characteristics while achieving high conductivity, overcoming the limitations of conventional carbonized aerogels

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If precise adjustment of carbon material dimensions is required, then the aerogel structure can be controlled, but the manufacturing complexity and cost increase

Engineering Contradiction:
Improveaerogel structure controlVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention removes the dimension adjustment step from the manufacturing process by utilizing the binder's phase conversion properties. The binder controls the aerogel structure formation during phase transition, eliminating the need for precise carbon material dimension control while maintaining manufacturing precision

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The binder performs self-organization during phase conversion, automatically forming the desired aerogel structure without external dimension control. This self-organizing capability simplifies the manufacturing process while ensuring consistent aerogel structure quality

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the production of carbon aerogels with enhanced specific surface area, conductivity, and mechanical properties, overcoming the limitations of conventional carbon aerogels by maintaining high conductivity and exhibiting desired pore characteristics without adjusting the carbon material's dimensions, thus facilitating their use in electrodes.

Implementation Method 1

mixing a binder which has a low carbonization ratio and is capable of performing phase conversion while using a carbon material

Methodology Applied
Scientific EffectPhase conversion: Phase Change

Implementation Method 2

mixing a carbon material and a dispersant with a solvent to prepare a carbon material dispersion

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

dipping the gel type carbon aerogel precursor in ethanol to remove the dispersant

Methodology Applied
Scientific EffectSupercritical fluid extraction: Supercritical Fluid Extraction

Data Source

PatentUS11203003B2Method of preparing carbon aerogel precursor, carbon aerogel precursor prepared thereby, and carbon aerogel
Publication Date: 2021.12.21 KOREA INST OF MATERIALS SCI
  • US11203003B2 patent drawing
  • US11203003B2 patent drawing
  • US11203003B2 patent drawing

AI summary

The present invention relates to a carbon aerogel precursor, a preparation method thereof and a carbon aerogel prepared thereby and, more particularly, to a carbon aerogel precursor which can be converted into a carbon aerogel that exhibits excellent specific surface area and physical properties by using a binder that has a low carbonization ratio and is capable of performing phase conversion while using a carbon material having physical properties such as diameter, length and the like that are not adjusted, a preparation method thereof, and a carbon aerogel prepared thereby.