Carbon Anode Oxygen Content for Battery Adhesion

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Solution Overview

Problem

Current secondary batteries face challenges in maintaining high capacity while ensuring adhesion between active material and current collector, and between active material particles, often requiring increased binder amounts which can reduce active material content.

Innovation Solution

A negative electrode with a high oxygen content of 700 mg/kg to 1,700 mg/kg in carbon-based particles enhances adhesion between the active material and current collector, and between active material particles, allowing for reduced binder usage and increased active material content, thereby improving battery capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the amount of binder is increased to improve adhesion between active material and current collector, then adhesion is improved, but the amount of active material particles is reduced and capacity is reduced

Engineering Contradiction:
Improveadhesion between active material and current collectorVSAvoidcapacity
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent changes the chemical composition parameters of the carbon-based particles by controlling the oxygen content within a specific range (700-1700 mg/kg). This parameter modification enables the carbon particles themselves to provide sufficient adhesion, eliminating the need to increase binder content and thus preserving active material quantity and capacity.

Inventive Principle:
Principle #35Parameter changes

2Strength

If the ratio of binder is increased to secure adhesion between active material particles, then adhesion is improved, but the amount of active material particles is reduced and capacity is reduced

Engineering Contradiction:
Improveadhesion between active material particlesVSAvoidcapacity
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

By modifying the oxygen content parameter of carbon-based particles to within 700-1700 mg/kg, the particles develop inherent adhesive properties that enable them to bond with each other effectively. This eliminates the need to increase binder ratio, thereby maintaining high active material content and capacity.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If the amount of active material particles is increased to improve capacity, then capacity is improved, but adhesion between active material and current collector deteriorates

Engineering Contradiction:
ImprovecapacityVSAvoidadhesion between active material and current collector
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent optimizes the oxygen content parameter of carbon-based particles to provide sufficient adhesion, which allows increasing the amount of active material particles without compromising adhesion. The modified carbon particles serve dual functions as both active material and adhesive agent.

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If the amount of active material particles is increased to improve capacity, then capacity is improved, but adhesion between active material particles deteriorates

Engineering Contradiction:
ImprovecapacityVSAvoidadhesion between active material particles
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

By controlling the oxygen content of carbon-based particles within 700-1700 mg/kg, the particles acquire enhanced surface properties that improve inter-particle adhesion. This enables high active material content to be maintained while ensuring sufficient adhesion between particles.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The high oxygen content in carbon-based particles improves adhesion, enabling higher battery capacity and reduced resistance, while maintaining efficient charge and discharge cycles.

Implementation Method 1

adhesion between active material and current collector and adhesion between active material particles may be improved due to a high oxygen content of carbon-based particles

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

the adhesion between the active material and the current collector and the adhesion between the active material particles may be secured even if the amount of a binder is reduced

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS10593937B2Anode and lithium secondary battery comprising the same
Publication Date: 2020.03.17 LG ENERGY SOLUTION LTD
  • US10593937B2 patent drawing

AI summary

The present invention relates to a negative electrode including an active material layer which includes carbon-based particles having an oxygen content of 700 mg/kg to 1,700 mg/kg, and a secondary battery including the same.