Carbon-Based Interconnects for Gap-Filling and Reliability

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Solution Overview

Problem

As integrated circuit feature sizes shrink, copper interconnect structures face challenges with gap-filling ability, electro migration, and increased resistivity due to size-dependent scattering effects, compromising manufacturing and reliability.

Innovation Solution

A self-selective, bottom-up growth method for carbon-based interconnect structures using 1-dimensional and 2-dimensional conduction features, eliminating the need for seed and barrier layers, and employing chemical vapor deposition instead of electrochemical plating, which enhances carrier transport and thermal conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If copper interconnect structures are used in reduced dimension trenches, then manufacturing is simplified, but gap-filling ability deteriorates and void formation occurs

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidgap-filling quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from copper to carbon-based materials (graphene, carbon nanotubes) to fundamentally alter the filling behavior in reduced dimension trenches, enabling complete gap-filling without void formation while maintaining manufacturing simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite carbon-based structures including graphene sheets and carbon nanotubes that combine the benefits of low resistivity with superior gap-filling capabilities, resolving the contradiction between manufacturing ease and filling quality

Inventive Principle:
Principle #40Composite materials

2Length of moving object

If copper interconnect dimensions are reduced, then device scaling is achieved, but resistivity increases due to size-dependent scattering effects

Engineering Contradiction:
Improveinterconnect dimensionVSAvoidresistivity
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The patent changes the material composition from copper to carbon-based materials, which maintain low resistivity even at reduced dimensions due to their unique electronic structure and ballistic transport properties, eliminating the size-dependent scattering effects that plague copper interconnects

Inventive Principle:
Principle #35Parameter changes

3Reliability

If copper interconnect structures are used, then electrical conduction is achieved, but electro migration compromises reliability

Engineering Contradiction:
Improveelectrical conductionVSAvoidelectro migration
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces copper with carbon-based materials that are inherently resistant to electro migration, effectively eliminating this harmful effect and improving long-term reliability without requiring additional protective measures

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The use of carbon-based composite materials (graphene, carbon nanotubes) provides both excellent electrical conduction and immunity to electro migration, simultaneously addressing both requirements

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If seed and barrier layers are added to copper interconnect structures, then manufacturing is improved, but device complexity increases

Engineering Contradiction:
Improvemanufacturing capabilityVSAvoidstructure complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent extracts and eliminates the seed and barrier layers from the interconnect structure by using carbon-based materials that can be directly deposited and patterned without requiring these additional functional layers, thereby reducing device complexity while maintaining or improving manufacturing capability

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves gap-filling in reduced dimension trenches, reduces electro migration, and increases current density while providing superior thermal conductivity, addressing the limitations of copper interconnects.

Implementation Method 1

a first conductive feature over the substrate and with materials of 1-dimensional conduction feature, a second conductive feature over the first conductive feature and with materials of 2-dimensional conduction feature

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

enhances carrier transport and thermal conductivity

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS9318439B2Interconnect structure and manufacturing method thereof
Publication Date: 2016.04.19 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US9318439B2 patent drawing
  • US9318439B2 patent drawing
  • US9318439B2 patent drawing

AI summary

The present disclosure provides an interconnect structure, including a substrate, a first conductive feature over the substrate, a second conductive feature over the first conductive feature, and a dielectric layer surrounding the first conductive feature and the second conductive feature. A width of the first conductive feature and a width of the second conductive feature are between 10 nm and 50 nm. The present disclosure also provides a method for manufacturing an interconnect structure, including (1) forming a via opening and a line trench in a dielectric layer, (2) forming a 1-dimensional conductive feature in the via opening, (3) forming a conformal catalyst layer over a sidewall of the line trench, a bottom of the line trench, and a top of the 1-dimensional conductive feature, and (4) removing the conformal catalyst layer from the bottom of the line trench and the top of the 1-dimensional conductive feature.