Carbon-Based Buffer Layer for Organic EL Devices

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Solution Overview

Problem

Organic electroluminescent (EL) devices face issues of poor efficiency, short life expectancy, and high power consumption, limiting their commercial implementation.

Innovation Solution

Incorporating a carbon-based buffer layer between the first electrode and the emission layer in organic EL devices, which can be doped with carbon-based compounds, to control the thickness and deposition rate of the buffer layer, thereby reducing driving voltage and enhancing life expectancy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional organic EL device structure is used, then the device can be manufactured with standard processes, but the device exhibits short life expectancy and high power consumption

Engineering Contradiction:
Improvelife expectancyVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

A buffer layer made of carbon-based compound (such as fullerene C60) is introduced as an intermediary layer between the first electrode and the emission layer. This buffer layer mediates the interaction between the electrode and emission materials, improving hole injection efficiency and reducing direct degradation reactions, thereby extending device life expectancy and reducing power consumption.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent uses composite material structures where the buffer layer combines carbon-based compounds with specific thickness control (0.1-100 nm). This composite approach at the nanoscale interface improves overall device performance by combining the benefits of carbon-based materials with precise thickness optimization to balance longevity and energy efficiency.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the buffer layer thickness is increased to improve hole injection, then hole injection efficiency improves, but the driving voltage increases

Engineering Contradiction:
Improvehole injection efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent optimizes the thickness parameter of the buffer layer within a specific range (0.1-100 nm). By controlling this critical parameter, the patent achieves optimal hole injection efficiency while preventing excessive driving voltage increase. The carbon-based compound in the buffer layer also modifies the energy band structure, enabling better hole injection at lower voltage penalties.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If emission materials with high efficiency are used, then light emission efficiency improves, but device life expectancy decreases due to material degradation

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidlife expectancy
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The carbon-based buffer layer acts as a protective intermediary between the first electrode and the emission layer. It prevents direct contact and degradation reactions between the electrode and emission materials, allowing high-efficiency emission materials to be used without suffering from rapid degradation, thus extending device life expectancy while maintaining high light emission efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbon-based buffer layer improves the efficiency and life expectancy of organic EL devices by optimizing the interfacial energy band gap and hole injection, resulting in lower driving voltage and extended device lifespan.

Implementation Method 1

forming a buffer layer including a carbon-based compound to a thickness of about 0.1 nm to about 100 nm on a first electrode

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentUS7811680B2Organic EL device and method of manufacturing the same
Publication Date: 2010.10.12 SAMSUNG DISPLAY CO LTD
  • US7811680B2 patent drawing
  • US7811680B2 patent drawing
  • US7811680B2 patent drawing

AI summary

An organic electroluminescent device is disclosed that includes an emission layer between a first electrode and a second electrode, and a buffer layer between the emission layer and the first electrode. The buffer layer includes a carbon-based compound and may be about 0.1 nm to about 100 nm thick. The organic electroluminescent device has greater driving voltage, better efficiency, and a longer life expectancy.