Carbon-Carbon Friction Material with Perforated Layer Reinforcement

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Solution Overview

Problem

Existing methods for producing carbon-carbon composites for friction units face issues such as low interlayer strength leading to delamination, high production costs due to complex needling technologies, and inhomogeneous material properties due to uncontrolled fiber orientation and dry mixing processes.

Innovation Solution

The method involves pre-perforating carbon fabric layers with holes larger than the fiber diameter, followed by suction of an aqueous suspension containing pitch binder and carbon fibers, which are then compressed and heat-treated to integrate fibers into the fabric layers without needling, ensuring increased interlayer strength and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional layering methods are used to produce carbon-carbon composites, then the production process is simple, but the interlayer strength is low leading to delamination

Engineering Contradiction:
Improveinterlayer strengthVSAvoiddelamination resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The carbon fabric layers are pre-perforated with holes before assembly, creating pathways that enable subsequent infiltration of carbon fibers through the layers during compression. This preliminary action ensures that the fiber reinforcement structure is established before final compaction, resolving the interlayer strength issue without requiring complex post-processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The pre-perforated fabric layers create a controlled porous structure with holes having linear dimensions significantly exceeding the carbon fiber filament diameter (L/d > 100). This porous architecture allows aqueous suspension to penetrate and deposit carbon fibers within the layer gaps, forming strong interlayer bonds that prevent delamination

Inventive Principle:
Principle #31Porous materials

2Strength

If needling technology is used to reinforce carbon-carbon composites, then interlayer connection is improved, but production cost increases significantly

Engineering Contradiction:
Improveinterlayer strengthVSAvoidproduction cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The mechanical needling process is replaced with a chemical-physical infiltration process where aqueous suspension containing carbon fibers is drawn through the pre-perforated layers by suction. This substitution eliminates expensive needling equipment while achieving comparable or superior interlayer bonding through fiber infiltration and binder consolidation

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

An aqueous suspension serving as an intermediary medium carries carbon fibers and pitch binder through the perforated fabric layers. The suspension acts as a vehicle that deposits reinforcing fibers into the layer interfaces and binds them together, achieving reinforcement without direct mechanical needling

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If dry mixing of components is used to manufacture friction materials, then the production process is simple, but fiber grinding and structural inhomogeneity occur

Engineering Contradiction:
Improveproduction simplicityVSAvoidstructural uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The mixing process parameters are fundamentally changed from dry mixing to wet mixing using aqueous suspension. This parameter change prevents fiber-grinding mechanical action while enabling uniform distribution of carbon fibers and pitch binder through fluid dynamics, eliminating structural inhomogeneity without sacrificing production simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Hydraulic principles are applied by using aqueous suspension to transport and deposit carbon fibers and binder materials. The liquid medium enables controlled infiltration through the perforated layers via suction, ensuring uniform material distribution and preventing the fiber damage associated with dry mechanical mixing

Inventive Principle:
Principle #29Pneumatics and hydraulics

4Volume of stationary object

If traditional pyrolytic compaction is used for friction materials, then density is achieved, but production time is long and final density remains low

Engineering Contradiction:
Improvematerial densityVSAvoidproduction cycle time
Core Design Contradiction:
Volume of stationary objectVSLoss of time

Solution Approach 1:

Carbon fibers are infiltrated into the fabric layers during the molding stage before pyrolysis, rather than relying solely on slow pyrolytic compaction to achieve density. This preliminary fiber placement and compression significantly reduces the time required for density achievement while maintaining or improving final density values

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The method creates a composite structure by infiltrating discrete carbon fibers into the fabric layers during molding, forming a hybrid architecture that achieves high density more rapidly. The combination of pre-formed fabric and infiltrated fibers creates a denser, more uniform structure that requires less time for pyrolytic compaction

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the shear strength of the composite material, reduces production costs, and maintains fine structure, achieving interlayer strengths of 25-30 MPa and friction coefficients between 0.3-0.5, with improved wear resistance and a shorter production cycle compared to existing methods.

Implementation Method 1

suction of an aqueous suspension containing pitch binder and carbon fibers

Methodology Applied
Scientific EffectSuction: Suction

Implementation Method 2

depositing fibers and binder into the holes to integrate layers

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 3

dried in a fixed state at the melting temperatures of the pitch binder

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 4

pressed at a temperature not less than twice the melting temperature of the pitch binder to the required thickness

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 5

the workpieces are carbonized, compacted, heat treated and mechanically processed

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentEP4305325B1A method for obtaining carbon-carbon material for heavily loaded friction units
Publication Date: 2024.05.01 3CM SIA
  • EP4305325B1 patent drawingFigure 1~2
  • EP4305325B1 patent drawingFigure 3

AI summary

The invention relates to the field of mechanical engineering, namely to heavily loaded friction units, such as brake systems of sports cars and other ground equipment. The proposed method for producing carbon-carbon material in the form of circular workpieces for use in heavily loaded friction units, contains the following steps: (i) impregnating the carbon fabric with a binder, preferably based on pitches, or in the initial state, exposing the carbon fabric to perforation by forming holes on it with linear size exceeding the diameter of the carbon fiber filament; (ii) assembling a press pack in a perforated sleeve by alternating laying of fabric cuts and sucking through them an aqueous suspension containing a pitch binder powder and carbon fiber filaments with a length of not more than 750 mkm; (iii) compressing the resulting wet press pack in the sleeve by at least ¼ of the original height and drying in a fixed state at the melting temperatures of the pitch binder to constant weight; (iv) pressing the resulting press pack at a temperature not less than twice the melting temperature of the pitch binder; (v) workpiece carbonization; (vi) workpiece compaction; (vi) heat treatment and (vii) mechanical processing in accordance with the drawing.