Carbon-Coated Li-Ion Cathode Material for Low-Temperature Output

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Solution Overview

Problem

Lithium ion batteries face poor output characteristics at low temperatures due to difficulties in lithium ion migration through carbon clusters, where existing carbonaceous films used in positive electrode materials are not optimal for low temperature performance.

Innovation Solution

A positive electrode material for lithium ion batteries is developed, comprising primary particles coated with a carbonaceous film or agglomerates, with specific powder resistance and carbon mass per unit specific surface area ranges, and a carbonaceous film thickness of 0.5 nm to 10 nm, primarily consisting of hard carbon, to enhance electron conductivity and lithium ion diffusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If lithium iron phosphate is coated with carbon to improve electron conductivity, then electron conductivity is improved, but lithium ion migration through gaps among carbon clusters becomes difficult, resulting in poor low temperature characteristics

Engineering Contradiction:
Improveelectron conductivityVSAvoidlithium ion migration
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies local quality by creating a core-shell structure where the central particle has different properties than the surface coating. The core maintains high electron conductivity while the surface layer is designed with specific porosity and composition to facilitate lithium ion migration. This local differentiation resolves the contradiction by optimizing each region for its specific function.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs porous materials by incorporating a surface layer with controlled porosity that allows lithium ion diffusion pathways. The porous structure creates gaps and channels that enable lithium ions to migrate efficiently even at low temperatures, while the overall coating maintains electron conductivity through the solid matrix.

Inventive Principle:
Principle #31Porous materials

2Power

If existing carbonaceous films are used to coat positive electrode material, then electron conductivity is enhanced, but low temperature output characteristics remain poor due to inadequate lithium ion diffusion

Engineering Contradiction:
Improveelectron conductivityVSAvoidlow temperature output characteristics
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The patent uses composite materials by combining multiple material phases in a hierarchical structure. The composite consists of a conductive core material surrounded by a surface layer with specific chemical composition and structural characteristics that facilitate both electron and ion transport. This composite approach allows simultaneous optimization of electron conductivity and lithium ion diffusion for improved low temperature performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies dimensionality change by transitioning from a simple 2D surface coating to a multi-layered hierarchical structure with distinct functional zones. The surface layer introduces additional dimensional complexity with its porous network and chemical gradient, creating three-dimensional pathways for lithium ion diffusion while maintaining the two-dimensional electron conduction pathways at the surface.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Reliability

If carbonaceous film thickness is increased to improve electron conductivity, then electron conductivity improves, but lithium ion diffusion pathways become restricted

Engineering Contradiction:
Improveelectron conductivityVSAvoidlithium ion diffusion path
Core Design Contradiction:
ReliabilityVSLength of moving object

Solution Approach 1:

The patent applies segmentation by dividing the coating into distinct functional layers: a core region and a surface layer with specific thickness and composition. This segmentation allows the core to provide structural stability and bulk conductivity while the thinner surface layer optimizes lithium ion access and diffusion pathways, resolving the contradiction between conductivity and ion transport.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs the nested doll principle by creating a hierarchical structure where the surface layer is nested around the core particle. The surface layer contains within it a network of pores and channels that provide lithium ion pathways, while the core provides the underlying conductive matrix. This nested arrangement allows simultaneous optimization of both electron conductivity and ion diffusion without requiring excessive coating thickness.

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly improves the output characteristics of lithium ion batteries at low temperatures by optimizing the carbonaceous film structure, ensuring adequate electron conductivity and lithium ion migration, thereby enhancing battery performance.

Implementation Method 1

a mass of the carbonaceous film per unit specific surface area is 0.7 mg/m2 or more and 1.1 mg/m2 or less... to enhance electron conductivity

Methodology Applied
Scientific EffectElectron conduction: Conduction (electrical)

Implementation Method 2

lithium ions are intercalated and deintercalated through gaps among carbon clusters... ensuring adequate... lithium ion migration

Methodology Applied
Scientific EffectIon diffusion: Diffusion

Data Source

PatentUS11831011B2Positive electrode material for lithium ion battery, positive electrode for lithium ion battery, and lithium ion battery
Publication Date: 2023.11.28 SUMITOMO METAL MINING CO LTD
  • US11831011B2 patent drawing

AI summary

To provide a positive electrode material for a lithium ion battery from which a lithium ion battery capable of enhancing output characteristics at low temperatures can be obtained, a positive electrode for a lithium ion battery in which the positive electrode material for a lithium ion battery is used, and a lithium ion battery including the positive electrode for a lithium ion battery. A positive electrode material for a lithium ion battery consisting of primary particles coated with a carbonaceous film or an agglomerate of the primary particles, in which a powder resistance Y is 500 Ω·cm or more and 50000 Ω·cm or less, a mass X of the carbonaceous film per unit specific surface area is 0.7 mg/m2 or more and 1.1 mg/m2 or less, and Formula (1) below is satisfied.Y≥4.91×106×e−9.021X  (1)