Carbon-Doped Semiconductor Layers for Boron Phosphorus Diffusion Control

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Solution Overview

Problem

The existing semiconductor memory devices face challenges in preventing the diffusion of boron and phosphorus dopants during high-temperature manufacturing processes, which can lead to deviations in threshold voltages and reduced transistor performance due to mutual diffusion through tungsten silicide in gate electrodes.

Innovation Solution

The semiconductor memory device incorporates semiconductor layers containing carbon to prevent boron and phosphorus diffusion, with a thin insulating layer to further suppress their penetration into conductive layers and the substrate, maintaining transistor characteristics and facilitating manufacturing processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high-temperature manufacturing processes are used, then manufacturing productivity is improved, but dopant diffusion increases causing threshold voltage deviation

Engineering Contradiction:
Improvemanufacturing productivityVSAvoidthreshold voltage precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

A carbon-containing semiconductor layer is introduced as an intermediary barrier between the dopant source and the tungsten silicide gate electrode. This intermediate layer prevents direct diffusion of boron and phosphorus into the gate electrode during high-temperature manufacturing processes, thereby maintaining threshold voltage precision while allowing high-productivity manufacturing to proceed.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The gate electrode structure is transformed from a simple tungsten silicide layer to a composite structure comprising multiple layers: the tungsten silicide gate electrode, an intermediate carbon-containing semiconductor layer, and an upper semiconductor layer. This composite structure provides diffusion barrier functionality while maintaining electrical characteristics, resolving the contradiction between high-temperature processing capability and dopant diffusion prevention.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional gate electrode structure is used, then device complexity is reduced, but dopant diffusion through tungsten silicide occurs

Engineering Contradiction:
Improvegate electrode structure complexityVSAvoidtransistor performance reliability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The gate electrode structure is segmented into distinct functional layers: the tungsten silicide gate electrode layer, an intermediate carbon-containing semiconductor layer serving as a diffusion barrier, and an upper semiconductor layer. This segmentation allows each layer to perform its specific function while maintaining overall structural simplicity and manufacturing feasibility.

Inventive Principle:
Principle #1Segmentation

3Manufacturing precision

If carbon-doped semiconductor layers are added, then dopant diffusion is suppressed, but manufacturing process complexity increases

Engineering Contradiction:
Improvedopant diffusion controlVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The carbon-containing semiconductor layer is formed by combining carbon doping with existing semiconductor layer formation processes. The carbon is introduced during standard semiconductor manufacturing steps, merging the diffusion barrier functionality with the existing process flow rather than adding entirely separate manufacturing steps, thereby limiting the increase in process complexity.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively suppresses the diffusion of boron and phosphorus, maintaining desired transistor performance and simplifying the manufacturing process by using carbon-doped semiconductor layers and a thin insulating layer to prevent dopant penetration.

Implementation Method 1

prevent the diffusion of boron and phosphorus dopants during high-temperature manufacturing processes

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

semiconductor layers containing carbon to prevent boron and phosphorus diffusion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS11380704B2Semiconductor memory device and method of manufacturing semiconductor memory device
Publication Date: 2022.07.05 KIOXIA CORP
  • US11380704B2 patent drawing
  • US11380704B2 patent drawing
  • US11380704B2 patent drawing

AI summary

A semiconductor memory device includes a P-type transistor and a first N-type transistor. The P-type transistor includes a first semiconductor layer containing carbon, a P-type second semiconductor layer provided on the first semiconductor layer, a third semiconductor layer provided on the second semiconductor layer and containing carbon. The first N-type transistor includes a fourth semiconductor layer containing carbon, an N-type fifth semiconductor layer provided on the fourth semiconductor layer, a sixth semiconductor layer provided on the fifth semiconductor layer and containing carbon.