Carbon Layer Plasma Etching With Boron Passivation for CD Uniformity

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Solution Overview

Problem

Current plasma etch technologies face challenges in etching high aspect ratio features in semiconductor devices, particularly with carbon containing masks, as they suffer from bowing, clogging, local CD uniformity issues, and throughput limitations, where optimizing one characteristic often worsens another.

Innovation Solution

A method involving a simultaneous etch and passivation step using a plasma formed from a boron containing passivant gas and an oxygen containing gas, which etches features in the carbon containing layer while minimizing bowing and clogging, and improving local CD uniformity and throughput.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional plasma etch processes are used to etch high aspect ratio features in carbon containing masks, then etching capability is achieved, but bowing and clogging occur which worsen manufacturing precision

Engineering Contradiction:
Improvefeature shape accuracyVSAvoidbowing and clogging
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

A boron-containing passivant gas is introduced as an intermediary substance that deposits on the sidewalls of the etched features, forming a protective layer that prevents carbon mask material from migrating and clogging the features, thereby eliminating bowing and improving feature shape accuracy

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The etch process parameters are changed by introducing a boron-containing passivant gas and optimizing the gas composition ratio, which alters the etching mechanism to reduce sidewall damage and prevent material migration, thus reducing bowing and clogging

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional etch processes are used, then etching is performed, but local CD uniformity and throughput are limited

Engineering Contradiction:
ImprovethroughputVSAvoidlocal CD uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The etch and passivation processes are merged into a single continuous step where boron-containing passivant gas is introduced during the etching process itself, eliminating the need for separate process steps and improving throughput while maintaining local CD uniformity through continuous sidewall protection

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The etching and passivation functions are combined into a single integrated process step, where the boron-containing passivant gas performs both etching assistance and sidewall protection simultaneously, increasing productivity without sacrificing local CD uniformity

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves improved ellipticity, reduced feature to feature CD variance, and increased throughput by using a single-step process that etches 90% to 100% of the feature depth, with boron containing passivation gas reducing sputtering and redeposition, thus enhancing defect performance and chip density.

Implementation Method 1

A plasma is created from the etch gas, wherein the plasma etches features in the carbon containing layer

Methodology Applied
Scientific EffectPlasma etching: Plasma

Implementation Method 2

boron containing passivation gas reducing sputtering and redeposition

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS20240379375A1Method and apparatus for etching a carbon containing layer
Publication Date: 2024.11.14 LAM RES CORP
  • US20240379375A1 patent drawing
  • US20240379375A1 patent drawing
  • US20240379375A1 patent drawing

AI summary

A method for etching features in a carbon containing layer below a mask is provided. A simultaneous etch and passivation step is provided comprising flowing an etch gas comprising a boron containing passivant gas and an oxygen containing gas. A plasma is created from the etch gas, wherein the plasma etches features in the carbon containing layer.