Carbon Implantation for Selective Substrate Etching

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Solution Overview

Problem

Current methods for structuring substrates, particularly for microelectronic and photovoltaic devices, are cumbersome and costly due to the need for multiple steps involving hard masks and lithography processes.

Innovation Solution

A method that uses carbon implantation to create a modified layer in the substrate, eliminating the need for hard masks and reducing the number of steps by forming reliefs through selective etching, where a protective screen is formed and carbon is implanted to create a resistant layer, allowing for direct etching without the need for lithography.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional hard mask deposition and lithography processes are used to structure substrates, then etching precision can be maintained, but the number of manufacturing steps and production cost increase significantly

Engineering Contradiction:
Improveetching precisionVSAvoidnumber of manufacturing steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the hard mask layer from the conventional structuring process. Instead of depositing a separate hard mask layer (such as silicon nitride or silicon oxide) and performing lithography to define patterns, the method directly implants carbon ions into the substrate to create the desired relief structures. This removal of the hard mask step significantly reduces the number of manufacturing steps while maintaining etching precision through the controlled carbon implantation process that creates modified layers with different etching rates.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces the mechanical/chemical deposition process of hard mask layers with an ion implantation process. Instead of depositing material to form a mask layer that is then patterned through lithography, carbon ions are directly implanted into the substrate to create the structural modifications needed for etching. This substitution eliminates the need for separate mask deposition, lithography, and mask removal steps, reducing process complexity while achieving the same functional outcome.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If multiple steps including hard mask deposition, lithography, and mask removal are used, then pattern definition accuracy is achieved, but manufacturing time and cost increase

Engineering Contradiction:
Improvepattern definition accuracyVSAvoidmanufacturing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The invention merges the functions of hard mask deposition, lithography pattern definition, and etching protection into a single carbon implantation step. The carbon implantation process simultaneously creates the pattern definition and the protective modified layer that will guide subsequent etching, eliminating the need for separate mask deposition, lithography exposure/development, and mask removal steps. This consolidation maintains pattern definition accuracy through precise ion implantation control while significantly reducing manufacturing time.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention performs the pattern definition action directly through carbon implantation before any etching process begins. The carbon ions are implanted to create modified layers with specific concentration profiles that will determine the final relief structure geometry. This preliminary action of direct implantation eliminates the need for subsequent mask removal steps, as the carbon-modified layers themselves serve as the etching masks throughout the process.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If conventional lithography and hard mask processes are employed, then substrate structuring can be achieved, but production cost increases due to multiple process steps

Engineering Contradiction:
Improvesubstrate structuring capabilityVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention extracts and eliminates the expensive hard mask deposition and lithography equipment and materials from the manufacturing process. By using direct carbon ion implantation to create the structuring patterns, the method removes the need for separate photolithography tools, photoresist materials, and hard mask deposition equipment. This extraction of unnecessary steps directly reduces production cost while maintaining substrate structuring capability through the precise control of ion implantation parameters.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the fundamental parameter of how patterns are defined on the substrate. Instead of using optical lithography parameters (wavelength, numerical aperture, photoresist chemistry), the method uses ion implantation parameters (ion energy, ion dose, implantation angle) to directly create the patterned modified layers. This parameter change enables a more direct and cost-effective manufacturing approach that eliminates multiple intermediate steps while achieving the same structuring results.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces the number of steps and costs associated with substrate structuring, enhancing efficiency and compatibility with existing microelectronics processes by eliminating the need for hard masks and lithography, while maintaining or improving etching precision.

Implementation Method 1

an implantation configured to introduce at least one species comprising carbon into the substrate from said face, the formation of a screen and the implantation being configured to form, in the substrate, at least one carbon modified layer having a concentration of implanted carbon greater than or equal to an etching threshold

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Data Source

PatentUS11495462B2Formation of reliefs on the surface of a substrate
Publication Date: 2022.11.08 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • US11495462B2 patent drawing
  • US11495462B2 patent drawing
  • US11495462B2 patent drawing

AI summary

A method for forming reliefs on a face of a substrate is provided, successively including forming a protective screen for protecting at least a first zone of the face; an implanting to introduce at least one species comprising carbon into the substrate from the face of the substrate, the forming of the protective screen and the implanting being configured to form, in the substrate, at least one carbon modified layer having a concentration of implanted carbon greater than or equal to an etching threshold only from a second zone of the face of the substrate not protected by the protective screen; removing the protective screen; and etching the substrate from the first zone selectively with respect to the second zone.