Carbon-Layer Electrolytic Capacitor for High-Voltage Gas Suppression

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Solution Overview

Problem

Electrolytic capacitors for high voltage applications face issues with gas generation due to thin dielectric oxide films, leading to swelling, leakage, and reduced lifetime, while adding gas absorption agents like nitro compounds compromises withstand voltage.

Innovation Solution

The electrolytic capacitor design includes a cathode foil with a carbon layer and a capacitance ratio of 10:1 between the anode and cathode sides, using a carbon layer on the cathode foil to suppress gas generation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the dielectric oxide film is thinned to increase capacitance, then capacitance increases, but gas generation increases and lifetime decreases

Engineering Contradiction:
ImprovecapacitanceVSAvoidlifetime
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

A carbon layer is introduced as an intermediary substance between the electrolytic solution and the cathode foil. This carbon layer acts as a mediator that suppresses gas generation at the cathode side while allowing the dielectric oxide film to be thin for high capacitance. The carbon layer absorbs or neutralizes gas molecules before they can accumulate and cause damage to the capacitor structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-generated harmful factors

If gas absorption agents like nitro compounds are added to suppress gas generation, then gas generation decreases, but withstand voltage decreases

Engineering Contradiction:
Improvegas generationVSAvoidwithstand voltage
Core Design Contradiction:
Object-generated harmful factorsVSStrength

Solution Approach 1:

The harmful function of gas absorption is extracted from the electrolytic solution (by removing nitro compounds) and transferred to a dedicated component - the carbon layer on the cathode foil. This separation allows the electrolytic solution to maintain its high voltage properties while the carbon layer specifically handles gas suppression without compromising withstand voltage.

Inventive Principle:
Principle #2Taking out (Extraction)

3Strength

If the dielectric oxide film is thickened to increase withstand voltage, then withstand voltage increases, but capacitance decreases

Engineering Contradiction:
Improvewithstand voltageVSAvoidcapacitance
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The invention changes the parameter of dielectric oxide film thickness to be thin (enabling high capacitance) while simultaneously changing the cathode side configuration (adding carbon layer) to compensate for gas generation issues. This parameter change allows operating at the optimal thin film thickness for capacitance without suffering from the usual gas generation problems.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design effectively suppresses gas generation, maintaining high voltage withstand and capacitance, thereby extending the capacitor's lifetime.

Implementation Method 1

dielectric oxide film which is formed on a surface of the enlarged surface layer

Methodology Applied
Scientific EffectDielectric polarization: Dielectric

Implementation Method 2

a carbon layer which is formed on the cathode foil

Methodology Applied
Scientific EffectGas absorption: Absorption (physical)

Implementation Method 3

The electrolytic solution intervenes between the anode foil and the cathode foil, closely contacts with an uneven surface of the anode foil, and acts as a true cathode

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Data Source

PatentUS12592347B2Electrolytic capacitor including an enlarged surface layer and a dielectric oxide film formed on the enlarged surface layer
Publication Date: 2026.03.31 NIPPON CHEMI CON CORP
  • US12592347B2 patent drawing
  • US12592347B2 patent drawing
  • US12592347B2 patent drawing

AI summary

The present disclosure provides an electrolytic capacitor for middle or high voltage application of 160 V or more, which can suppress the total amount of gas generated inside the electrolytic capacitor. An electrolytic capacitor includes anode foil on which dielectric oxide film is formed, and a cathode body. The cathode body includes cathode foil formed of valve action metal and a carbon layer formed on the cathode foil. The anode foil and the cathode body have capacitance so that when capacitance X of the anode foil per unit area is 1, ratio of capacitance Y of the cathode body per the same unit area is equal to or more than 10.