Carbon-Modified SiGe Epitaxial Growth for PFET Defect Reduction

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional processes for fabricating transistors with epitaxially grown silicon/germanium materials in integrated circuits face significant defects, leading to variations in transistor characteristics and performance, particularly due to the challenges of achieving precise material composition and layer thickness, which affects the threshold voltage and strain conditions.

Innovation Solution

Incorporating a carbon species at the interface between the silicon/germanium alloy and the silicon base material during selective epitaxial growth to reduce defect rates and enhance the crystalline quality, allowing for superior flexibility in setting threshold voltages and strain conditions, thereby improving transistor performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional selective epitaxial growth is used to form silicon/germanium material, then transistor performance can be improved through strain induction, but defect rates increase significantly

Engineering Contradiction:
Improvetransistor performanceVSAvoiddefect rate
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

A carbon-containing intermediate layer is introduced between the silicon base material and the silicon/germanium alloy layer. This intermediate layer acts as a mediator that facilitates epitaxial growth while reducing defect formation, allowing the strain-inducing silicon/germanium material to be incorporated without the previously observed significant defect rates

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The chemical composition parameters of the epitaxial growth atmosphere are changed by introducing carbon-containing compounds (such as methane or carbon monoxide). This parameter change modifies the growth conditions to produce fewer defects while maintaining the strain-inducing properties of the silicon/germanium material

Inventive Principle:
Principle #35Parameter changes

2Reliability

If higher germanium concentrations are used to enhance strain conditions, then charge carrier mobility improves, but defect rates increase

Engineering Contradiction:
Improvecharge carrier mobilityVSAvoiddefect rate
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The carbon-containing intermediate layer enables the incorporation of higher germanium concentrations by mediating the epitaxial growth process. It allows the silicon/germanium alloy to form with reduced defects even at elevated germanium content, thereby enabling enhanced strain conditions and improved charge carrier mobility without the prohibitive defect rates that would otherwise occur

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If precise control of material composition and layer thickness is achieved, then threshold voltage control improves, but process complexity increases

Engineering Contradiction:
Improvethreshold voltage controlVSAvoidprocess complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The carbon-containing intermediate layer enables a more self-regulating epitaxial growth process. By providing a stable foundation that reduces defects, it allows for more precise and controllable formation of subsequent layers, improving threshold voltage control while actually simplifying the overall process by reducing the need for complex defect management

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The incorporation of carbon significantly reduces defect rates by up to ten times, enabling more precise control over material characteristics, resulting in improved transistor performance and reduced variations, allowing for higher germanium concentrations and enhanced strain conditions.

Implementation Method 1

Conventional processes for fabricating transistors with epitaxially grown silicon/germanium materials in integrated circuits face significant defects

Methodology Applied
Scientific EffectEpitaxial growth: Epitaxy

Implementation Method 2

Incorporating a carbon species at the interface between the silicon/germanium alloy and the silicon base material during selective epitaxial growth to reduce defect rates

Methodology Applied
Scientific EffectCarbon incorporation: Chemical Vapour Deposition

Data Source

PatentUS8939765B2Reduction of defect rates in PFET transistors comprising a Si/Ge semiconductor material formed by epitaxial growth
Publication Date: 2015.01.27 GLOBALFOUNDRIES US INC
  • US8939765B2 patent drawing
  • US8939765B2 patent drawing
  • US8939765B2 patent drawing

AI summary

In sophisticated semiconductor devices, the defect rate that may typically be associated with the provision of a silicon/germanium material in the active region of P-channel transistors may be significantly decreased by incorporating a carbon species prior to or during the selective epitaxial growth of the silicon/germanium material. In some embodiments, the carbon species may be incorporated during the selective growth process, while in other cases an ion implantation process may be used. In this case, superior strain conditions may also be obtained in N-channel transistors.