Carbon Nanostructure Growth via Segmented Catalyst Oxidation

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Solution Overview

Problem

Existing methods for producing carbon nanostructures face challenges in controlling the growth direction of carbon nanofilaments, leading to structural defects and limited elongation, with previous techniques either resulting in bending or premature termination of filament growth.

Innovation Solution

A method involving a carburizing gas feed, oxidizing gas feed, heating, and separation steps between a base body and a separable body, using carburizable metals, where the separable body is moved away from the base body, with controlled carburization and decarburization to promote consistent growth of carbon nanostructures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a carbon nanostructure is produced by feeding raw-material gas to fine catalyst particles while heating, then carbon nanotubes can be grown, but the growth direction cannot be controlled leading to structural defects

Engineering Contradiction:
Improvegrowth direction controlVSAvoidstructural defects
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The catalyst is divided into multiple small particles arranged in a specific pattern on the substrate, with gaps positioned between them. This segmentation allows carbon nanofilaments to grow in controlled directions between the catalyst particles, preventing bending and structural defects while maintaining reliable growth orientation.

Inventive Principle:
Principle #1Segmentation

2Length of moving object

If a carbon nanofilament is grown between cut surfaces of oxidized catalyst pieces, then elongation can be achieved, but growth terminates prematurely

Engineering Contradiction:
Improvefilament elongationVSAvoidgrowth duration
Core Design Contradiction:
Length of moving objectVSDuration of action of moving object

Solution Approach 1:

The catalyst particles are pre-oxidized and arranged in a specific configuration with gaps between them before the carbon nanofilament growth process begins. This preliminary arrangement ensures that carbon can continuously supply from the catalyst particles through the gaps, enabling sustained elongation without premature growth termination.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If the catalyst is oxidized and divided into pieces, then carbon nanofilaments can grow between cut surfaces, but the process complexity increases

Engineering Contradiction:
Improvefilament position controlVSAvoidprocess steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The oxidation and division steps are merged into a single integrated process where catalyst particles are oxidized and simultaneously arranged in the desired configuration with gaps between them. This combination reduces process complexity while maintaining precise control over filament growth positions between the catalyst pieces.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables consistent and controlled growth of carbon nanostructures with reduced structural defects and extended elongation, preventing premature termination and ensuring high-quality production.

Implementation Method 1

a carburizing gas feed step in which a carburizing gas is fed to at least a portion of the base body at which the base body and the separable body are joined to or in contact with each other

Methodology Applied
Scientific EffectCarburization: Carburizing

Implementation Method 2

an oxidizing gas feed step in which an oxidizing gas is fed to at least a part of a portion of the base body which is other than the portion of the base body to which the carburizing gas is fed

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

a heating step in which the portion of the base body at which the base body and the separable body are joined to or in contact with each other is heated

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS11220432B2Method for producing carbon nanostructure and apparatus for producing carbon nanostructure
Publication Date: 2022.01.11 SUMITOMO ELECTRIC INDUSTRIES LTD
  • US11220432B2 patent drawing
  • US11220432B2 patent drawing
  • US11220432B2 patent drawing

AI summary

A method for producing a carbon nanostructure according to an aspect of the present invention is a method in which a carbon nanostructure is produced between a base body and a separable body while the separable body is relatively moved away from the base body, the base body including a carburizable metal that is a principal constituent, the separable body including a carburizable metal that is a principal constituent, the separable body being joined to or in contact with the base body in a linear or strip-like shape. The method includes a carburizing gas feed step, an oxidizing gas feed step, a heating step in which the portion of the base body at which the base body and the separable body are joined to or in contact with each other is heated, and a separation step in which the separable body is relatively moved away from the base body.