Carbon Nanotube Diffusion Layer for Fuel Cell MEA

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Solution Overview

Problem

The existing proton exchange membrane fuel cells have reduced reaction activity due to non-uniform dispersion of carbon fibers in the diffusion layer and high electrical resistance, which hinders gas diffusion and electron travel.

Innovation Solution

A membrane electrode assembly using a uniformly distributed carbon nanotube structure as the diffusion layer, which includes ordered or disordered carbon nanotubes, and a catalyst layer with metal particles, enhancing gas diffusion and electron conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If carbon fiber paper is used as the diffusion layer, then the structure is simple and easy to manufacture, but the carbon fibers are not uniformly dispersed and have high electrical resistance

Engineering Contradiction:
Improveease of manufactureVSAvoidreaction activity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the material parameters of the diffusion layer from conventional carbon fiber paper to carbon nanotube-based materials. This parameter change achieves uniform dispersion of conductive components and significantly improves electrical conductivity, thereby enhancing reaction activity while maintaining ease of manufacture through established coating processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining carbon nanotubes with conductive polymers or metals in the diffusion layer. This composite structure leverages the superior electrical conductivity and uniform dispersion characteristics of carbon nanotubes while maintaining structural integrity and ease of manufacturing through conventional techniques

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If carbon fiber paper is used as the diffusion layer, then the manufacturing process is simple, but the micropores are not uniform and gas diffusion is hindered

Engineering Contradiction:
Improveease of manufactureVSAvoiduniformity of micropores
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the structural parameters of the diffusion layer by using carbon nanotube networks instead of carbon fiber mats. This creates uniformly distributed micropores with controlled size and distribution, achieving precise gas diffusion pathways while maintaining simple manufacturing through solution coating and drying processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes porous carbon nanotube structures with controlled porosity and uniform pore distribution. The nanoscale dimensions and self-organizing properties of carbon nanotubes naturally create uniform micropore structures that facilitate consistent gas diffusion, while the manufacturing process remains simple and scalable

Inventive Principle:
Principle #31Porous materials

3Device complexity

If carbon fiber paper is used as the diffusion layer, then the structure is straightforward, but electron travel is restricted due to high electrical resistance

Engineering Contradiction:
Improvestructure complexityVSAvoidelectron conductivity
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent changes the electrical conductivity parameter of the diffusion layer by incorporating carbon nanotubes, which have inherently superior electrical conductivity compared to carbon fiber paper. This parameter improvement enables efficient electron transport throughout the electrode structure while maintaining a straightforward and simple device architecture

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent makes the diffusion layer multi-functional by using carbon nanotube-based materials that simultaneously provide mechanical support, uniform micropore structure for gas diffusion, and high electrical conductivity for electron transport. This eliminates the need for separate components, simplifying the overall device structure while improving performance

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbon nanotube structure improves the uniform diffusion of gases and electron conductivity, thereby increasing the reaction activity and efficiency of the fuel cell.

Implementation Method 1

the micropores therein defined by the carbon fibers are not uniform. Thus, such structure prevents the diffusion layer from uniformly diffusing the gases that are needed for the MEA

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

the carbon fiber paper has high electrical resistance, thereby the travel of electrons between the diffusion layer and the external electrical circuit is restricted

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS9362569B2Membrane electrode assembly and fuel cell using the same
Publication Date: 2016.06.07 HON HAI PRECISION INDUSTRY CO LTD
  • US9362569B2 patent drawing
  • US9362569B2 patent drawing
  • US9362569B2 patent drawing

AI summary

A membrane electrode assembly includes a proton exchange membrane having two surfaces, and two electrodes separately located on the two surfaces. At least one of the two electrodes comprises a carbon nanotube composite structure, the carbon nanotube composite structure includes a carbon nanotube structure and a catalyst material dispersed in the carbon nanotube structure. The carbon nanotube structure is a planar structure including a plurality of carbon nanotube wires located side by side, crossed, or weaved together to form the carbon nanotube structure. Each of the plurality of carbon nanotube wires includes a plurality of carbon nanotubes aligned around an axis of the carbon nanotube twisted wire in a helix way.