Carbon Nano-Tube Tip Alignment via Grooved Metallic Electrode

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Solution Overview

Problem

Conventional methods for manufacturing carbon nano-tube tips face challenges in controlling the direction, diameter, length, and adhesion strength of carbon nano-tubes, leading to inefficient alignment and multiple tube formations, which hinder precise manipulation and application in nano-scale devices.

Innovation Solution

An apparatus and method utilizing a metallic vessel with a groove as an electrode, combined with AC/DC voltage supply and specific solvents, to control the alignment and length of carbon nano-tubes during electrophoresis, ensuring a uniform electric field and improved adhesion through heat treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional electrophoresis methods are used with flat electrodes, then carbon nano-tubes can be attached to the tip, but the direction and alignment of carbon nano-tubes cannot be controlled precisely, resulting in multiple tube formations and poor alignment

Engineering Contradiction:
Improvealignment precision of carbon nano-tubesVSAvoidelectrode structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The electrode is segmented into multiple independent needle-like electrodes arranged in an array, with each electrode capable of being independently controlled. This segmentation allows precise control over the electric field distribution, enabling accurate alignment and direction control of carbon nano-tubes during electrophoresis, while avoiding the formation of multiple unaligned tubes that occur with conventional flat electrodes.

Inventive Principle:
Principle #1Segmentation

2Productivity

If arc discharge method is used to manufacture carbon nano-tubes, then carbon nano-tubes can be produced, but large amounts of amorphous carbon particles and graphite particles are simultaneously formed, creating a mixture that is difficult to separate

Engineering Contradiction:
Improvecarbon nano-tube production efficiencyVSAvoidpurity of carbon nano-tubes
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The method changes the physical-chemical parameters of the carbon source material by using solubilized carbon materials (such as carbon black, graphite powder, or amorphous carbon) dispersed in organic solvents instead of solid graphite rods used in arc discharge. This parameter change enables carbon nano-tube growth through chemical vapor deposition with significantly reduced formation of amorphous carbon and graphite particles, producing high-purity carbon nano-tubes without the separation difficulties associated with arc discharge methods.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If chemical vapor deposition is used with hydrocarbon gases, then carbon nano-tubes can be grown, but the process requires complex catalytic metal deposition and drying steps

Engineering Contradiction:
Improvesimplicity of manufacturing processVSAvoidcarbon nano-tube growth efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention uses organic solvents (such as toluene, benzene, or carbon disulfide) as intermediaries to dissolve carbon materials, creating stable carbon-containing solutions that can be directly applied to catalytic metal substrates. This intermediary approach eliminates the need for separate catalytic metal deposition and drying steps required in conventional chemical vapor deposition, simplifying the manufacturing process while maintaining high carbon nano-tube growth efficiency through direct immersion or coating methods.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables precise control over the direction and alignment of carbon nano-tubes, resulting in a single, straight tip with enhanced adhesion strength, suitable for nano-probe applications and improved electrical conductivity.

Implementation Method 1

utilizing a metallic vessel with a groove as an electrode, combined with AC/DC voltage supply and specific solvents, to control the alignment and length of carbon nano-tubes during electrophoresis

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Implementation Method 2

ensuring a uniform electric field and improved adhesion through heat treatment

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS7959781B2Apparatus and method for manufacturing carbon nano-tube probe by using metallic vessel as an electrode
Publication Date: 2011.06.14 RES & BUSINESS FOUND SUNGKYUNKWAN UNIV
  • US7959781B2 patent drawing
  • US7959781B2 patent drawing
  • US7959781B2 patent drawing

AI summary

The present invention provides an apparatus for manufacturing a carbon nano-tube tip comprising an AC/DC voltage supply, a metallic or semiconductor tip, an amperemeter, and a metallic vessel connected to the tip and the amperemter, wherein the metallic vessel is used as the electrode and define a groove therein filled with a carbon nano-tube solution. The present invention also provides a method for manufacturing a carbon nano-tube tip wherein carbon nano-tubes dispersed in a solvent are attached by electrophoresis to the end of a metal tip or semiconductor tip by using as an electrode a metallic vessel having a groove therein.