Porous Carbon-Conductive Polymer Composite Electrode

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Solution Overview

Problem

Existing electrode materials for electrochemical elements, such as lithium ion secondary batteries and electric double-layer capacitors, do not achieve optimal electrostatic capacitance when scaled up for production.

Innovation Solution

A carbon material with a specific surface area of 750 to 3000 m2/g, methylene blue adsorption performance of 150 mL/g or more, and a Raman spectrum with at least three peaks in the 1250 to 1700 cm−1 range, combined with a conductive polymer, is used as the electrode material to enhance electrostatic capacitance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional electrode materials are used for scaled-up production, then manufacturing cost is reduced, but electrostatic capacitance is insufficient

Engineering Contradiction:
Improveelectrostatic capacitanceVSAvoidmanufacturing complexity
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent uses a composite material consisting of porous carbon particles and conductive polymer particles. The porous carbon provides high surface area for charge storage, while the conductive polymer enhances electron transport. This composite structure achieves high electrostatic capacitance in scaled-up production by combining the advantages of both materials without requiring complex manufacturing processes.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies using porous carbon particles with a specific surface area of 0.5 to 3.0 cm³/g. The porous structure provides extensive surface area for electrostatic charge accumulation, directly improving electrostatic capacitance. The pore structure also facilitates electrolyte penetration and ion transport, enhancing overall performance in scaled-up electrochemical elements.

Inventive Principle:
Principle #31Porous materials

2Quantity of substance

If high surface area carbon material is used, then electrostatic capacitance is improved, but charging and discharging speed may be reduced

Engineering Contradiction:
Improveelectrostatic capacitanceVSAvoidcharging and discharging speed
Core Design Contradiction:
Quantity of substanceVSSpeed

Solution Approach 1:

The patent merges porous carbon particles with conductive polymer particles to create a composite where the porous carbon provides high surface area for charge storage and the conductive polymer provides rapid electron transport pathways. This combination resolves the contradiction by enabling both high electrostatic capacitance and fast charging/discharging speeds simultaneously.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The conductive polymer acts as an intermediary between the porous carbon particles and the electrolyte. It facilitates rapid electron transport from the carbon surface to the current collector, preventing the high surface area carbon material from becoming a bottleneck for charge transfer, thus maintaining fast charging and discharging speeds.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbon material with specific properties and a conductive polymer composite achieves higher electrostatic capacitance in electrochemical elements, maintaining semi-permanent and high-speed charging and discharging properties.

Implementation Method 1

methylene blue adsorption performance of 150 mL/g or more

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

obtained by bonding the conductive polymer to the surface of the porous carbon material

Methodology Applied
Scientific EffectSurface bonding: Adhesive

Implementation Method 3

after mixing the conductive polymer and the porous carbon material, undoping by heat treatment at a temperature at least 20° C. lower than the decomposition temperature of the conductive polymer

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS10128505B2Carbon material, electrode material using same and method of manufacturing same
Publication Date: 2018.11.13 SIKA HAMATITE CO LTD
  • US10128505B2 patent drawing
  • US10128505B2 patent drawing

AI summary

A method of manufacturing a carbon material comprising a composite of a porous carbon material and a conductive polymer, in which a dispersion solution of the porous carbon material and a dispersion solution of the conductive polymer are mixed to make the composite of the porous carbon material and the conductive polymer. The carbon material has: a specific surface area of 750 to 3000 m2/g, a methylene blue adsorption performance of 150 mL/g or more, and at least three peaks in a range 1250 to 1700 cm−1 of a spectrum obtained by laser Raman spectroscopy with an excitation wavelength of 532 nm.