Carbon-Silicon Composite Anode for High-Capacity Lithium Batteries

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Solution Overview

Problem

Conventional carbonaceous anode materials in lithium secondary batteries have limited capacity and poor output characteristics, especially during high-rate charging, and alloy-based materials face issues with electrical conductivity and volume expansion, hindering their commercialization.

Innovation Solution

A carbon/silicon composite anode active material is developed, featuring spherical carbon particles with a first carbon coating layer, a silicon coating layer with amorphous silicon nanoparticles, and a second carbon coating layer, which enhances specific surface area, electrical conductivity, and stability, while controlling volume expansion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If alloy-based material is used to increase capacity, then capacity is improved, but electrical conductivity is reduced and volume expansion occurs

Engineering Contradiction:
ImprovecapacityVSAvoidelectrical conductivity and structural stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent embeds silicon nanoparticles inside carbon particles, creating a core-shell structure where the silicon core provides high capacity while the carbon shell maintains electrical conductivity and structural stability. This nested configuration allows the alloy-based material to achieve high capacity without suffering from the typical drawbacks of poor conductivity and severe volume expansion.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The patent creates a composite material system combining silicon nanoparticles with carbon particles, where each component compensates for the other's deficiencies. The silicon provides high capacity while the carbon matrix provides electrical conductivity and structural framework, resulting in a composite that overcomes the limitations of pure alloy-based materials.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional carbonaceous anode material is used, then structural stability is maintained, but capacity is limited to theoretical maximum

Engineering Contradiction:
Improvestructural stabilityVSAvoidcapacity
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent applies local quality by creating regions with different properties within the carbon particle - the interior contains silicon nanoparticles for high capacity while the outer carbon shell provides structural stability. This spatial differentiation of material properties allows the anode to simultaneously achieve high capacity and structural stability.

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If alloy-based material undergoes volume expansion during charging, then capacity is improved, but electrode plate damage occurs

Engineering Contradiction:
ImprovecapacityVSAvoidelectrode plate integrity
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent provides beforehand cushioning by surrounding silicon nanoparticles with a carbon shell that acts as a buffer against volume expansion. The carbon shell absorbs and distributes the mechanical stress generated during charging and discharging cycles, preventing electrode plate damage before it occurs.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The carbon shell surrounding the silicon nanoparticles acts as a flexible protective layer that can accommodate volume changes of the silicon core during lithium insertion and extraction. This flexible shell structure maintains electrode integrity while allowing the high-capacity silicon to undergo necessary volume expansion.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbon/silicon composite anode active material achieves higher capacity (400-800 mAh/g) and improved lifetime and output characteristics, addressing the limitations of conventional carbonaceous anode materials.

Implementation Method 1

a first carbon coating layer present on surfaces of the carbon particles

Methodology Applied
Scientific EffectCoating: Coatings

Implementation Method 2

an alloy-based material having a high capacity... A conventional carbonaceous anode active material has merely a theoretical capacity of about 372 mAh/g

Methodology Applied
Scientific EffectAlloying:

Implementation Method 3

a second carbon coating layer present on the silicon coating layer

Methodology Applied
Scientific EffectCoating: Coatings

Implementation Method 4

A lithium secondary battery, which is charged and discharged through oxidation/reduction of lithium ions

Methodology Applied
Scientific EffectOxidation-reduction: Redox Reactions

Data Source

PatentEP3309873B1Anode active material for lithium secondary battery, preparation method therefor, and lithium secondary battery containing same
Publication Date: 2020.05.27 SJ MATERIALS CO LTD
  • EP3309873B1 patent drawingFigure 1
  • EP3309873B1 patent drawingFigure 2
  • EP3309873B1 patent drawingFigure 3

AI summary

An anode active material for a lithium secondary battery, a preparation method thereof, and a lithium secondary battery including the anode active material are provided. The anode active material includes carbon particles having a spherical shape, a first carbon coating layer present on surfaces of the carbon particles, a silicon coating layer present on the first carbon coating layer and including silicon nanoparticles, and a second carbon coating layer present on the silicon coating layer.