Source/Drain Carbon Implant for Boron Diffusion Control

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Solution Overview

Problem

In CMOS manufacturing, boron out-diffusion from PMOS source/drain regions leads to short channel effects and voltage threshold roll-off, which is not adequately controlled by existing methods, causing damage to the sidewalls and bottom of recessed regions and resulting in reduced device performance.

Innovation Solution

Incorporating a barrier dopant, such as carbon, into the remaining portion of the source and drain regions to retard boron out-diffusion, combined with a reduced pocket implant dose and nitrogen incorporation during annealing to repair damage and passivate interfaces, effectively reducing boron diffusion into the channel region.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high concentration boron doping is incorporated into e-SiGe to reduce sheet resistance and contact resistance in source drain regions, then electrical conductivity is improved, but boron out-diffusion into the channel region increases causing short channel effects

Engineering Contradiction:
Improveelectrical conductivityVSAvoidboron out-diffusion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A carbon barrier layer is introduced as an intermediary between the boron-doped e-SiGe source/drain regions and the channel. This carbon layer acts as a diffusion barrier that prevents boron atoms from migrating into the channel region while allowing the high boron concentration to remain in the source/drain regions for low resistance contacts.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies different doping concentrations and material compositions to different regions: high boron concentration in the e-SiGe source/drain regions for conductivity, carbon enrichment at the interface for barrier function, and appropriate channel doping. This local differentiation allows each region to optimize its specific function without compromising others.

Inventive Principle:
Principle #3Local quality

2Reliability

If high dose pocket implants are used to counteract boron out-diffusion, then short channel effects are reduced, but damage to the sidewalls and bottom of recessed source/drain regions increases

Engineering Contradiction:
Improveshort channel effect controlVSAvoidsidewall and bottom damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The carbon barrier layer serves as a mediator that eliminates the need for high-dose pocket implants. By providing a physical barrier to boron diffusion, the carbon layer allows the use of lower, less damaging implant doses while still achieving effective short channel effect control.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the potential harm of boron diffusion into a benefit by using the carbon barrier to control and direct boron distribution. The boron remains confined to where it is needed (source/drain regions) for low resistance, while the carbon barrier prevents its harmful migration into the channel.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-generated harmful factors

If carbon is implanted to form a barrier to retard boron out-diffusion, then boron diffusion is reduced, but implant damage may occur requiring repair annealing

Engineering Contradiction:
Improveboron out-diffusionVSAvoidimplant damage
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The carbon implant is performed as a preliminary step before e-SiGe deposition and pocket implants. This preliminary carbon barrier formation protects against subsequent boron diffusion, and any implant damage is addressed through repair annealing processes that restore the crystal structure before final device formation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The carbon barrier layer is established beforehand to cushion against boron diffusion. The subsequent rapid thermal annealing process serves to repair any damage from the carbon implant and activate the barrier layer, ensuring it functions effectively before the boron-containing e-SiGe is deposited.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a 30% reduction in drain-induced barrier lowering, lower e-SiGe resistance, and reduced gate edge damage, improving short channel effects and device performance by minimizing boron out-diffusion and enhancing the integrity of the source/drain regions.

Implementation Method 1

A barrier dopant is incorporated into a remaining portion of the source and drain regions to retard boron out-diffusion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

nitrogen incorporation during annealing to repair damage and passivate interfaces

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 3

Boron doping may be incorporated into the e-SiGe for lower sheet resistance and contact resistance in the source drain regions

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 4

growing an epitaxial layer of SiGe within recesses in the source/drain regions

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 5

lattice mismatch creates a uni-axial compressive stress within the channel region

Methodology Applied
Scientific EffectStress:

Data Source

PatentUS7838887B2Source/drain carbon implant and RTA anneal, pre-SiGe deposition
Publication Date: 2010.11.23 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US7838887B2 patent drawing
  • US7838887B2 patent drawing
  • US7838887B2 patent drawing

AI summary

A semiconductor device system, structure, and method of manufacture of a source/drain to retard dopant out-diffusion from a stressor are disclosed. An illustrative embodiment comprises a semiconductor substrate, device, and method to retard sidewall dopant out-diffusion in source/drain regions. A semiconductor substrate is provided with a gate structure, and a source and drain on opposing sides of the gate structure. Recessed regions are etched in a portion of the source and drain. Doped stressors are embedded into the recessed regions. A barrier dopant is incorporated into a remaining portion of the source and drain.