Carbonate Detergent Softening via Chelating Agent and Cationic Polymer

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Solution Overview

Problem

Existing carbonate-built detergent compositions face challenges in maintaining fabric softening benefits over multiple washes while ensuring effective cleaning performance, particularly with low levels of phosphate and zeolite builders to avoid environmental issues and cloudy wash liquor formation.

Innovation Solution

Incorporating a chelating agent, neutralized soap, and a cationically substituted quaternary ammonium polymer in a carbonate-based builder system, with a concentration of 15wt.% to 40wt.% carbonate, to enhance fabric softening and cleaning performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If fabric softening components are added to carbonate-built detergent composition, then fabric softness is improved, but softening benefits are undermined over multiple washes

Engineering Contradiction:
Improvefabric softnessVSAvoidduration of softening benefit
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The patent combines multiple fabric softening components (cationic polymer, silicone, clay) with specific carbonate builders (sodium carbonate, potassium carbonate) and chelating agents to create a composite detergent system. This composite formulation maintains fabric softness over multiple washes by synergistic interaction between components, preventing the rapid degradation seen with single-component systems.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the concentration ranges of key components: cationic polymer (0.1-5%), silicone (0.1-5%), clay (0.1-5%), and carbonate builders (20-40%). By precisely controlling these parameters, the formulation achieves sustained softening benefits through balanced chemical interactions that remain stable across multiple wash cycles.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If phosphate builders and zeolite builders are increased to improve cleaning performance and softening, then cleaning performance is improved, but environmental friendliness deteriorates and cloudy wash liquor forms

Engineering Contradiction:
Improvecleaning performanceVSAvoidenvironmental impact and wash liquor clarity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts or removes harmful phosphate builders and zeolite builders from the detergent formulation, replacing them with environmentally friendly alternatives. The formulation achieves cleaning performance without phosphates (0-2%) and minimal zeolites (0-5%), using carbonate builders and organic builders instead, thereby eliminating cloudy wash liquor formation and environmental damage.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses biodegradable organic builders (citrate, gluconate, lactate) that are environmentally benign and do not persist in the environment like phosphates and zeolites. These organic builders provide temporary water softening and cleaning enhancement without long-term environmental accumulation or wash liquor cloudiness.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly improves fabric softening benefits while maintaining cleaning performance, even at lower concentrations of fabric softening agents, and reduces the need for high phosphate and zeolite levels, addressing environmental concerns and wash liquor clarity issues.

Implementation Method 1

the presence of a chelating agent and a neutralized soap leads to significantly enhanced fabric softening benefits

Methodology Applied
Scientific EffectChelation:

Implementation Method 2

incorporating fabric softening component that impart a fabric softening benefit to the laundered fabric

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP4073216B1Detergent composition
Publication Date: 2023.08.09 UNILEVER IP HLDG BV
  • EP4073216B1 patent drawing
  • EP4073216B1 patent drawing
  • EP4073216B1 patent drawing

AI summary

The present invention relates to a detergent composition. More particularly, the invention is directed to a softening in the wash laundry composition. It is seen that in a carbonate-built detergent composition, the softening properties of a fabric softening component on the fabric reduces over multiple washes and there is a desire to further improve the softening benefits on fabric in wash. Moreover, there is a need to provide softening detergent compositions while maintaining the cleaning performance. It is thus an object of the present invention to provide a detergent composition capable of imparting improved softness and cleaning performance to fabrics treated during the wash cycle of a laundering process. It is found by the present inventors that the presence of a chelating agent and a neutralized soap leads to significantly enhanced fabric softening benefits in a carbonate-built laundry detergent composition having a cationic polymer whilst maintaining good cleaning performance.