Carbonated Waste-to-Energy Ash Aggregates for Road Construction

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Solution Overview

Problem

The use of waste-to-energy bottom ash (BA) in road construction is limited due to environmental concerns and strength issues, primarily caused by hydrogen gas generation and heavy metal leaching, which affect the suitability of WTE BA as a recycled material in Portland Cement Concrete (PCC) and Hot Mix Asphalt (HMA) compositions.

Innovation Solution

The development of compositions and methods involving the separation and alteration of WTE BA aggregates to specific sizes and compositions, reducing aluminum content and reacting them with CO2 to form stable carbonated aggregates, which are then integrated into PCC and HMA mixtures, thereby reducing hydrogen gas formation and heavy metal leaching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If WTE bottom ash is used as aggregate in road construction, then waste recycling and energy recovery are improved, but hydrogen gas generation and heavy metal leaching occur causing environmental harm

Engineering Contradiction:
Improvewaste recycling efficiencyVSAvoidhydrogen gas generation and heavy metal leaching
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary action by treating WTE bottom ash with carbon dioxide before use in road construction. This pre-treatment carbonates the ash, transforming reactive aluminum and calcium compounds into stable carbonate forms that prevent hydrogen gas generation and heavy metal leaching during subsequent road construction activities

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the chemical parameters of WTE bottom ash by reacting it with carbon dioxide to alter its composition. This transformation modifies the ash from a reactive state that generates hydrogen gas and leaches heavy metals to a carbonated state with reduced reactivity and improved environmental safety

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If WTE bottom ash is used in Portland cement concrete compositions, then aggregate availability is improved, but hydrogen gas generation occurs compromising structural integrity

Engineering Contradiction:
Improveaggregate availabilityVSAvoidstructural integrity
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent applies preliminary action by carbonating WTE bottom ash before incorporating it into Portland cement concrete. This pre-treatment removes the aluminum compounds that react with cement to generate hydrogen gas, thereby preserving the structural integrity of the concrete while maintaining aggregate availability

Inventive Principle:
Principle #10Preliminary action

3Productivity

If WTE bottom ash is used in hot mix asphalt compositions, then recycled material content is improved, but heavy metal leaching occurs affecting environmental safety

Engineering Contradiction:
Improverecycled material contentVSAvoidheavy metal leaching
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of WTE bottom ash through carbonation treatment, which stabilizes heavy metals and prevents their leaching into the environment. This parameter change allows the ash to be safely used in hot mix asphalt compositions while maintaining high recycled material content

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution enhances the structural integrity and environmental safety of road construction materials by minimizing hydrogen gas generation and heavy metal leaching, making WTE BA more suitable for widespread use in road construction applications.

Implementation Method 1

The WTE BA aggregate fraction can be reacted with CO2 from a CO2 source

Methodology Applied
Scientific EffectCarbonation reaction: Chemical Bonding

Data Source

PatentUS12091827B2Waste to energy ash and engineered aggregate in road construction
Publication Date: 2024.09.17 UNIV OF FLORIDA RESEARCH FOUNDATION INC
  • US12091827B2 patent drawing
  • US12091827B2 patent drawing
  • US12091827B2 patent drawing

AI summary

Described herein are compositions and methods for waste-to-energy ash in engineered aggregate in road construction.