Carbonitriding Metal Parts via Segmented Nitriding and Carburizing

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Solution Overview

Problem

Existing carbonitriding processes fail to adequately enhance the tempering resistance, hardness, and wear resistance of metal parts, as nitrogen enrichment is limited to the surface area, leading to inhomogeneous properties and insufficient depth penetration.

Innovation Solution

A low-pressure carbonitriding method where the metal part is heated, then nitrided with a nitrogen donor gas followed by carburization, with a temperature equalization phase to reduce temperature gradients, allowing nitrogen to diffuse deeply and carbon to occupy interstitial sites, thereby increasing resistance and hardness throughout the metal part.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If nitriding is performed after or during the last carburizing phase, then nitrogen is enriched in the surface area, but the nitrogen diffusion depth is smaller than the carburization depth, resulting in insufficient tempering resistance and hardness in the carburized area

Engineering Contradiction:
Improvenitrogen enrichmentVSAvoidnitriding depth
Core Design Contradiction:
Quantity of substanceVSLength of stationary object

Solution Approach 1:

The patent applies preliminary action by performing nitriding during the heating phase and/or before the final carburizing phase, ensuring nitrogen is introduced into the metal part before the carburization process completes. This timing allows nitrogen to diffuse to greater depths while carbon diffusion is still occurring or completing, thereby achieving both deep nitrogen penetration and sufficient surface carbon enrichment without the limitation of performing nitriding only after carburizing

Inventive Principle:
Principle #10Preliminary action

2Quantity of substance

If nitriding is performed during the heating phase, then nitrogen can be introduced into the metal part, but temperature gradients within the metal part or batch lead to inhomogeneous tempering resistance, hardness, strength and/or wear resistance

Engineering Contradiction:
Improvenitrogen introductionVSAvoidhomogeneity of properties
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent segments the heat treatment process into distinct phases: a heating phase with initial nitriding, a temperature equalization phase where nitrogen diffusion continues at constant temperature, and a carburizing phase. This segmentation allows nitrogen to be introduced early while temperature gradients equalize during the intermediate phase, ensuring homogeneous nitrogen distribution before carbon diffusion begins, thereby achieving both nitrogen introduction and property homogeneity

Inventive Principle:
Principle #1Segmentation

3Stability of the object's composition

If a temperature equalization phase is introduced between heating and nitriding, then temperature gradients are reduced and homogeneous properties are achieved, but the process time is extended

Engineering Contradiction:
Improvetemperature uniformityVSAvoidprocess duration
Core Design Contradiction:
Stability of the object's compositionVSLoss of time

Solution Approach 1:

The patent merges the temperature equalization phase with the nitriding phase by continuing nitrogen diffusion during the entire equalization period at constant temperature. This combination eliminates the need for a separate post-equalization nitriding step, as the nitrogen diffusion that would have occurred in a traditional sequential process is accomplished during the merged phase, thereby achieving temperature uniformity without extending total process time

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves improved tempering resistance, hardness, and wear resistance by ensuring nitrogen and carbon diffusion to deeper layers, reducing nitrogen effusion, and maintaining consistent properties across the metal part, enhancing its performance under mechanical stress at elevated temperatures.

Implementation Method 1

the metal part is heated to a treatment temperature in a heating phase

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

nitrided with a nitrogen donor gas in at least one nitriding phase

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

carburized with a carbon donor gas in at least one carburizing phase

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 4

the treatment temperature is used to equalize the temperature within the metal part or between several metal parts

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentEP2430210B1Method for carbonitriding
Publication Date: 2018.01.24 ROBERT BOSCH GMBH
  • EP2430210B1 patent drawingFigure 1

AI summary

The invention relates to a method for carbonitriding at least one metal part in which the metal part is heated to a treatment temperature in a heating phase (1), is nitrided with a nitrogen donor gas in at least one nitriding phase (2a-2d) and is carburized with a carbon donor gas in at least one carburizing phase (3a-3d). Said method is characterised in that the first nitriding phase (2a) begins once the heating phase (1) has finished and prior to the beginning of the first carburizing phase (3a).