Carboxylate Resist Composition for Lower Mask Error Factor

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Solution Overview

Problem

Existing resist compositions form resist patterns with high mask error factors (MEF), which affect the precision and accuracy of the patterning process.

Innovation Solution

A carboxylate represented by formula (I) and a resin with a structural unit represented by formula (IP) are used in resist compositions to improve the mask error factor (MEF) of the resist patterns.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If existing resist compositions are used, then the resist pattern can be formed, but the mask error factor (MEF) is high which degrades pattern accuracy

Engineering Contradiction:
Improvepattern accuracyVSAvoidmask error factor
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the resin by introducing specific structural units with formula (IP) containing carboxylate groups at defined positions. This structural modification alters the resist composition's properties to reduce MEF and improve pattern accuracy

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite resist composition by combining the newly designed resin with specific structural units with formula (IP) and carboxylate compounds with formula (I). This composite approach synergistically improves both MEF and pattern accuracy beyond what individual components could achieve

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS12619145B2Carboxylate, carboxylic acid generator, resin, resist composition and method for producing resist pattern
Publication Date: 2026.05.05 SUMITOMO CHEM CO LTD
  • US12619145B2 patent drawing
  • US12619145B2 patent drawing
  • US12619145B2 patent drawing

AI summary

A carboxylate represented by formula (I), a resin comprising a structural unit derived from the carboxylate represented by formula (I), a resit composition comprising the carboxylate represented by formula (I) or a resin comprising a structural unit derived from the carboxylate represented by formula (I).