Electrophotographic Carrier Core Composition for Stable Resistance

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Solution Overview

Problem

Current magnetic core materials for electrophotographic developers face challenges in maintaining stable electric resistance and strength over environmental variations, leading to image defects and reduced durability, especially in high-speed printing applications.

Innovation Solution

A magnetic core material with controlled specific anion components and pore volume, within specific ranges, to minimize environmental dependency of electric resistance and enhance mechanical strength, combined with a resin-coated carrier for improved performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional magnetic core materials are used, then the developer can be manufactured, but the electric resistance varies with environmental conditions leading to image defects

Engineering Contradiction:
Improvestability of electric resistanceVSAvoidenvironmental variation effects
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the magnetic core material by controlling the content of specific anion components (fluorine, chlorine, bromine, nitrite, nitrate, sulfate) within defined ranges. This parameter optimization minimizes the material's sensitivity to environmental variations in temperature and humidity, thereby stabilizing electric resistance and preventing image defects such as white spots and fogging.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite magnetic core materials with specific compositions including ferrite-based compounds combined with controlled amounts of various anion components. This composite structure creates a material that maintains stable electrical properties across different environmental conditions, resolving the contradiction between reliability and environmental sensitivity.

Inventive Principle:
Principle #40Composite materials

2Strength

If the carrier particle strength is increased, then durability is improved, but the compression breaking strength varies under different conditions

Engineering Contradiction:
Improvecompression breaking strengthVSAvoidstrength consistency
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent optimizes the compositional parameters of the magnetic core material, specifically controlling the content of additive elements and anion components. This parameter control enhances the structural integrity and strength consistency of the carrier particles, ensuring that compression breaking strength remains stable under varying operational conditions and extending developer life.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If trace elements are reduced in the carrier core material, then carrier characteristics are improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvecarrier characteristicsVSAvoidimpurity control precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent establishes specific numerical ranges for the content of anion components and additive elements in the magnetic core material. By defining these compositional parameters with clear upper and lower limits, the patent achieves improved carrier characteristics while maintaining feasible manufacturing precision requirements, avoiding overly stringent control that would complicate production.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a carrier with stable electric resistance and high compression breaking strength, reducing environmental variation effects and ensuring high-quality images over extended printing periods.

Implementation Method 1

a carrier particle is a carrier substance which is agitated with a toner particle in a development box filled with the developer

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 2

resin-filled ferrite carriers in which resin is filled in voids of a ferrite carrier core material using porous ferrite particles

Methodology Applied
Scientific EffectPorosity: Porosity

Data Source

PatentEP3582022B1Magnetic core material for electrophotographic developer, carrier for electrophotographic developer, and developer
Publication Date: 2024.03.13 POWDERTECH CO LTD
  • EP3582022B1 patent drawingFigure 1
  • EP3582022B1 patent drawing
  • EP3582022B1 patent drawing

AI summary

Provided are a magnetic core material for electrophotographic developer and a carrier for electrophotographic developer, which have a small change of the electric resistance caused by environmental differences and excellent strength with low specific gravity and with which a satisfactory image free of defects can be obtained, and a developer containing the carrier. A magnetic core material for electrophotographic developer, satisfying a value of Expression (1): a + b × 10 + c + d + e + f, being from 200 to 1,400, when an amount of fluorine ion is denoted by a (ppm), an amount of chlorine ion is denoted by b (ppm), an amount of bromide ion is denoted by c (ppm), an amount of nitrite ion is denoted by d (ppm), an amount of nitrate ion is denoted by e (ppm), and an amount of sulfate ion is denoted by f (ppm), which are measured by combustion ion chromatography; and having a pore volume of from 30 to 100 mm3/g.