Water-Based Carrier Fluid Stabilization Against Premature Polymer Reaction

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Solution Overview

Problem

Water-based treatment fluids used in subterranean operations, such as hydraulic fracturing, suffer from premature polymer reactions due to increased ambient temperatures, leading to instability and inefficiency.

Innovation Solution

A water-based carrier-fluid system comprising a brine saturated with specific salts, viscoelastic surfactants, and salt crystals is developed, where the order of addition ensures that all water is bound, preventing premature polymer reactions by maintaining stability across varying temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If water-based treatment fluids use polymers to alter physical properties, then the treatment fluid can achieve desired functions (viscosity, suspension capability, friction reduction), but the polymer reacts prematurely due to increased ambient temperature, causing instability

Engineering Contradiction:
Improvepolymer functionalityVSAvoidfluid stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent extracts the harmful element (water) from the treatment fluid system by using oil-based carrier fluids instead of water-based fluids. This eliminates the premature polymer reaction problem while preserving all desired polymer functions for viscosity modification, suspension capability, and friction reduction in subterranean operations

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the fundamental parameter of the carrier fluid from water-based to oil-based. This parameter change prevents polymer hydrolysis and premature reaction while maintaining the ability to achieve desired physical properties through polymer addition, thereby resolving the contradiction between adaptability and reliability

Inventive Principle:
Principle #35Parameter changes

2Productivity

If cross-linked polymer is used to increase viscosity for proppant transport, then proppant transport efficiency improves, but the polymer reacts prematurely causing loss of control over fluid properties

Engineering Contradiction:
Improveproppant transport efficiencyVSAvoidpolymer reaction control
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

By removing water from the carrier fluid system and replacing it with oil-based fluids, the patent eliminates the cause of premature polymer reaction. This allows cross-linked polymers to maintain their structural integrity and provide consistent proppant transport efficiency without unpredictable viscosity changes or gelation

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs polymers in oil-based carrier fluids that remain stable during storage and transport, providing reliable proppant transport capability when needed. The oil-based system prevents premature degradation, ensuring the polymer's functionality is preserved until actually deployed in subterranean operations

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Loss of energy

If friction reducing polymer is used in slickwater fracturing to minimize energy loss, then energy efficiency improves, but the polymer often results in increased friction when cross-linked

Engineering Contradiction:
Improvefrictional energy lossVSAvoidfriction increase
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The patent removes water from the carrier fluid and replaces it with oil-based fluids, eliminating the chemical environment that causes unwanted friction when polymers cross-link. This allows friction-reducing polymers to function as intended, minimizing energy loss during pumping operations without generating harmful friction increases

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The oil-based carrier fluid acts as an intermediary between the friction-reducing polymer and the subterranean formation. This intermediary prevents the harmful interactions that occur in water-based systems, allowing the polymer to reduce friction and energy loss without causing the opposite effect through unwanted cross-linking reactions

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system maintains stability and delays polymer reactions, ensuring consistent performance and efficiency in subterranean operations even at elevated temperatures.

Implementation Method 1

a water-based carrier-fluid system comprising: a brine formed from water saturated with at least one saturation salt

Methodology Applied
Scientific EffectSaturation: Supersaturation

Implementation Method 2

a viscoelastic surfactant

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 3

The friction reducing polymer facilitates laminar flow of the treatment fluid, which causes less frictional forces and energy loss than turbulent flow of the same fluid

Methodology Applied
Scientific EffectLaminar flow: Laminar Flow

Data Source

PatentUS12441929B2Treatment fluid stabilized to prevent polymer reaction
Publication Date: 2025.10.14 HALLIBURTON ENERGY SERVICES INC
  • US12441929B2 patent drawing
  • US12441929B2 patent drawing

AI summary

A water-based carrier-fluid system comprising a brine formed from water saturated with at least one saturation salt, a viscoelastic surfactant, and one or more salt crystals. The water-based carrier-fluid system is formed by adding the viscoelastic surfactant to the brine to produce a first mixture prior to the one or more salt crystals being added to the mixture. The salt in the salt crystals has a Ksp value equal to or greater than the saturation salt.