Case-Hardened Steel Pipe Workability via Normalizing and Annealing

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Solution Overview

Problem

Case hardening steel tubes face challenges with high hardness leading to poor workability, dimensional inaccuracies, and reduced impact fracture strength due to coarse grain formation during carburizing and quenching, especially under high-temperature conditions.

Innovation Solution

A process involving normalizing steel tubes at 880-980°C, followed by cold working and stress relief annealing at 700-820°C, which spheroidizes pearlite to control hardness and improve workability, while maintaining a ferrite + pearlite structure to prevent excessive hardness and grain coarsening.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high temperature carburizing (990-1090°C) is employed to shorten carburizing time, then productivity is improved, but coarse grains develop causing deterioration of fatigue properties and impact fracture strength

Engineering Contradiction:
Improvecarburizing timeVSAvoidfatigue properties and impact fracture strength
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the steel, specifically controlling C content at 0.15-0.30%, Si at 0.20-0.40%, Mn at 0.30-0.90%, Cr at 0.50-0.90%, Mo at 0.15-1.00%, and adding B at 0.0005-0.0050%, to enable successful carburizing at lower temperatures (900-980°C) while maintaining high productivity and avoiding coarse grain formation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces Boron (B) as an intermediary element that enhances hardenability and allows carburizing to be performed at lower temperatures, thereby acting as a mediator between the conflicting requirements of short carburizing time and fine grain structure maintenance

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If high strength case hardening steel is produced to improve wear resistance and fatigue strength, then surface hardness is improved, but workability deteriorates due to high hardness

Engineering Contradiction:
Improvesurface hardness and fatigue strengthVSAvoidworkability during forging
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies local quality by creating a case hardening structure where the surface layer has high hardness (58-65 HRC) for wear resistance while the base metal maintains lower hardness for good workability, achieving different properties in different regions of the same material

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent performs preliminary carburizing and quenching treatment to create the hardened surface layer before final machining operations, ensuring that the high strength properties are established in advance while allowing subsequent operations to benefit from the hardened surface

Inventive Principle:
Principle #10Preliminary action

3Strength

If carbon content is increased to improve strength and hardness, then surface hardness is improved, but toughness and impact fracture resistance deteriorate

Engineering Contradiction:
Improvesurface hardnessVSAvoidtoughness and impact fracture resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent optimizes the carbon content parameter to a moderate range of 0.15-0.30%, avoiding excessive carbon that would harm toughness, while compensating for surface hardness requirements through controlled carburizing and the addition of alloying elements like Cr, Mo, and B that enhance hardenability without sacrificing base metal toughness

Inventive Principle:
Principle #35Parameter changes

4Reliability

If B is added to prevent carbide precipitation and improve hardenability, then impact fracture strength is improved, but manufacturing cost increases

Engineering Contradiction:
Improveimpact fracture strengthVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes the Boron content parameter to a small but effective range of 0.0005-0.0050%, achieving the desired impact fracture strength and hardenability improvement with minimal addition, thereby controlling manufacturing cost while maintaining the beneficial effects of Boron

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process achieves a case hardening steel tube with HRB hardness of 72-80, enhancing workability and impact fracture resistance without sacrificing dimensional accuracy, by adjusting the proportion of spheroidized pearlite and controlling cooling rates.

Implementation Method 1

subjecting the steel tube to normalizing by holding for 30 seconds to 30 minutes at a temperature of 880 - 980 °C followed by cooling

Methodology Applied
Scientific EffectNormalizing: Heat Treatment

Implementation Method 2

performing cold working of the normalized steel tube with a reduction in area of 20 to 50% and then annealing the cold worked steel tube at a temperature of 700 - 820 °C

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 3

The part which has been formed is then subjected to surface hardening treatment such as carburizing or carbo-nitriding

Methodology Applied
Scientific EffectCarburizing: Carburizing

Implementation Method 4

carburizing and quenching treatment

Methodology Applied
Scientific EffectQuenching: Heat Treatment

Data Source

PatentEP2135962B1Case-hardened steel pipe excellent in workability and process for production thereof
Publication Date: 2016.07.13 NIPPON STEEL & SUMITOMO METAL CORP
  • EP2135962B1 patent drawingFigure 1

AI summary

A case hardening steel tube which has a hardness of 72 - 80 HRB and which gives a carburized layer with a high strength and high wear resistance and adequate resistance to impact fracture when it is formed into a final product by working and subsequent carburizing and quenching under relatively mild conditions is manufactured by forming a tube from a steel having a steel composition comprising, in mass percent, C: 0.1 - 0.25%, Si: 0.2 - 0.4%, Mn: 0.3 - 0.9%, P: at most 0.02%, S: 0.001 - 0.15%, Cr: 0.5 - 0.9%, Mo: 0.15 - 1%, Al: 0.01 - 0.1%, B: 0.0005 - 0.009%, N: less than 0.006%, and a remainder essentially of Fe, then subjecting the resulting steel tube to normalizing by soaking at a temperature of 880 - 980 °C followed by cooling at a cooling rate of at most 70 °C per minute, carrying out cold working of the normalized steel tube, and then annealing the cold worked steel tube at a temperature of 700 - 820 °C.