Castable Refractory Material for Aluminium Thimbles

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Solution Overview

Problem

Conventional refractory materials used in aluminium processing, such as cement-bonded fused silica, have limited durability and require frequent replacement in DC casting systems, leading to inefficiencies and increased maintenance costs.

Innovation Solution

A castable refractory material comprising fused silica, ceramic fibre, microsilica, and colloidal silica, with a dispersing agent and non-wetting additive, providing enhanced strength, thermal shock resistance, and machinability, allowing for the production of refractory products with improved durability and longevity in aluminium processing environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cement-bonded fused silica refractory material is used for thimbles, then good resistance to erosion from molten aluminium is achieved, but operational life is limited to approximately 500 casts

Engineering Contradiction:
Improveresistance to erosionVSAvoidoperational life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent applies composite materials by combining fused silica aggregate with a colloidal silica binder system instead of traditional cement bonding. This creates a refractory composite that maintains erosion resistance while significantly extending operational life from 500 to over 800 casts. The composite structure integrates refractory aggregate particles within a silica-based matrix that provides both mechanical strength and chemical stability against molten aluminium.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical and physical parameters of the bonding system by replacing cement with colloidal silica. This parameter change transforms the binder from a calcium-based cement to a silicon-based colloidal system that cures to form a more durable, erosion-resistant matrix. The colloidal silica provides different bonding characteristics and thermal stability that directly address the limited operational life of conventional cement-bonded refractories.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional castable refractory materials are used, then manufacturing simplicity is maintained, but machining precision and dimensional consistency are difficult to achieve

Engineering Contradiction:
Improvecasting simplicityVSAvoiddimensional consistency
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by incorporating a dispersing agent into the castable refractory mixture before casting. This dispersing agent pre-prevents particle agglomeration and ensures uniform distribution of refractory aggregates throughout the matrix. By addressing particle distribution in advance, the material achieves both ease of casting and high machining precision, as the uniform structure allows for consistent dimensional control during subsequent machining operations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent substitutes mechanical mixing and compaction methods with a chemical dispersion system. Instead of relying on mechanical forces to achieve uniform particle distribution, the dispersing agent chemically stabilizes the slurry to prevent settling and agglomeration. This substitution enables the material to be easily cast while maintaining the particle uniformity necessary for precise machining and consistent dimensions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If ceramic fibre is used in the refractory material, then thermal shock resistance is improved, but health risks increase due to soluble fibre

Engineering Contradiction:
Improvethermal shock resistanceVSAvoidhealth risks
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful aspect of soluble ceramic fibre into a benefit by utilizing the solubility characteristic. The soluble ceramic fibre is intentionally included to provide excellent thermal shock resistance, and its solubility is leveraged during the curing process where water extraction creates a controlled porous structure that enhances thermal performance. The fibre's solubility, which could be harmful, is transformed into a useful feature for achieving the desired thermal properties and microstructure.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent utilizes porous materials by incorporating soluble ceramic fibre that creates a controlled porous microstructure during curing. As the soluble fibre dissolves or is extracted, it leaves behind a porous network that improves thermal shock resistance by reducing thermal gradients and stress. This intentional porosity, created through the soluble fibre's decomposition, provides thermal benefits while the fibre itself is selected to minimize health risks.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new refractory material significantly extends the operational life of components like thimbles from 500 casts to over 800 casts, reduces health risks due to soluble fibre, and enables precise machining for consistent dimensions, while maintaining resistance to erosion and thermal stress.

Implementation Method 1

a bonding material comprising colloidal silica

Methodology Applied
Scientific EffectColloidal silica bonding: Chemical Bonding

Implementation Method 2

with a dispersing agent

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

non-wetting additive

Methodology Applied
Scientific EffectNon-wetting: Wetting

Data Source

PatentEP3134371B1Castable refractory material
Publication Date: 2019.09.25 PYROTEK ENG MATERIALS
  • EP3134371B1 patent drawingFigure 1
  • EP3134371B1 patent drawingFigure 2
  • EP3134371B1 patent drawingFigure 3~6

AI summary

A castable refractory material for use in the manufacture of refractory products includes fused silica, ceramic fibre, microsilica and a bonding material comprising colloidal silica.