Oxidation Catalyst Diagnosis via Hydrocarbon Sensor

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Solution Overview

Problem

Existing methods for diagnosing the deterioration of oxidation catalysts in diesel engine exhaust systems, particularly in O2-excessive atmospheres, face challenges due to low measurement accuracy and indirect diagnosis techniques, which result in errors and reduced fuel economy.

Innovation Solution

A method involving a hydrocarbon gas sensor placed downstream of the oxidation catalyst in the exhaust path, which detects the concentration of unburned hydrocarbon gases under controlled conditions, comparing it with threshold values based on catalyst temperature to accurately diagnose deterioration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If temperature difference measurement method is used to diagnose oxidation catalyst deterioration, then diagnosis can be performed indirectly, but measurement precision is poor due to large errors from exhaust gas temperature and flow rate changes

Engineering Contradiction:
Improvediagnosis capabilityVSAvoidmeasurement accuracy
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent replaces the indirect thermal field measurement method (temperature difference) with a direct chemical field measurement method (hydrocarbon concentration detection). By substituting the measurement principle from thermal sensing to chemical sensing, the system achieves direct quantification of catalyst performance without being affected by exhaust gas temperature and flow rate variations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces a hydrocarbon gas sensor as an intermediary measurement device that directly detects unburned hydrocarbon concentrations downstream of the oxidation catalyst. This intermediary sensor provides a direct link between catalyst performance and measurement, eliminating the need for indirect inference through temperature differences.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If fuel injection is used to accelerate heat generation for diagnosis, then catalyst conversion capability can be assessed, but fuel economy deteriorates due to large fuel injection amount

Engineering Contradiction:
Improvediagnosis accuracyVSAvoidfuel consumption
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent utilizes the engine's own exhaust gas, which naturally contains unburned hydrocarbons from incomplete combustion, as the test substance for catalyst diagnosis. By leveraging the self-generated hydrocarbon content in the exhaust stream, the system eliminates the need for external fuel injection to create test conditions, thereby avoiding additional fuel consumption.

Inventive Principle:
Principle #25Self-service

3Reliability

If wide-range oxygen concentration sensors are used to diagnose catalyst deterioration, then oxygen consumption can be measured, but measurement precision is insufficient due to low accuracy in detecting small oxygen consumption changes

Engineering Contradiction:
Improvediagnosis capabilityVSAvoiddetection accuracy
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent changes the measurement parameter from oxygen concentration (which changes only slightly during oxidation) to hydrocarbon concentration (which shows significant changes). By measuring the concentration of unburned hydrocarbons instead of oxygen consumption, the system achieves much higher detection sensitivity and measurement precision for catalyst performance assessment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for real-time, accurate diagnosis of oxidation catalyst deterioration, enhancing measurement precision and reducing fuel consumption by directly measuring unburned hydrocarbon concentrations, thereby improving diagnostic accuracy and fuel efficiency.

Implementation Method 1

a hydrocarbon gas sensor placed downstream of the oxidation catalyst in the exhaust path, which detects the concentration of unburned hydrocarbon gases

Methodology Applied
Scientific EffectCatalytic combustion: Combustion

Implementation Method 2

an oxidation catalyst with a function of oxidizing unburned hydrocarbon gases in an exhaust gas from the internal combustion engine

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS10196958B2Catalyst deterioration diagnosis method
Publication Date: 2019.02.05 NGK INSULATORS LTD
  • US10196958B2 patent drawing
  • US10196958B2 patent drawing
  • US10196958B2 patent drawing

AI summary

A method for diagnosing the degree of deterioration of a catalyst disposed in an exhaust path of an internal combustion engine and oxidizes or adsorbs a target gas, including at least one of a hydrocarbon gas and a carbon monoxide gas in an exhaust gas from the internal combustion engine, is adapted to determine whether deterioration exceeding an acceptable level of a catalyst occurs or not by comparing the concentration of a target gas detected downstream from the catalyst in the exhaust path when a diagnosis-gas atmosphere containing a target gas higher in concentration than a target gas during a steady-operation state of the internal combustion engine is intentionally produced and introduced into the catalyst with a threshold value corresponding to the temperature of a catalyst at the timing which the diagnosis-gas atmosphere is introduced.