Catalyst Fines Detection in Heavy Fuel Oil

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Solution Overview

Problem

Existing methods for detecting catalyst fines in heavy fuel oil (HFO) are either expensive, time-consuming, or inadequate for simple, low-cost monitoring, which is critical for preventing engine damage due to the presence of these fines.

Innovation Solution

A method involving a diluent composition with a non-polar solvent and an aqueous reagent composition containing a water-soluble inorganic salt and base, which allows phase separation to facilitate the detection of catalyst fines by inspecting the aqueous phase for their presence, using a kit that includes these components and optionally a phase transfer agent to enhance separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If sophisticated equipment using spectroscopy (NMR, XRF) is used to detect catalyst fines, then measurement precision is improved, but device complexity and cost increase significantly

Engineering Contradiction:
Improvedetection accuracy of catalyst finesVSAvoidcomplexity of detection equipment
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs disposable test strips impregnated with reagents that react with catalyst fines, replacing expensive, complex spectroscopic equipment with simple, single-use diagnostic tools that provide sufficient accuracy for the application

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent replaces complex mechanical/optical spectroscopic systems with a simple chemical reaction-based colorimetric test that can be performed visually or with basic photometric equipment

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If existing detection methods are used, then measurement precision is improved, but loss of time increases due to complex procedures

Engineering Contradiction:
Improvedetection accuracy of catalyst finesVSAvoidtime required for detection
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The test strips are pre-impregnated with reagents and prepared in advance, allowing for rapid on-site testing without requiring complex sample preparation or lengthy analysis procedures

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The disposable nature of the test strips eliminates time-consuming equipment calibration, maintenance, and complex operational procedures associated with sophisticated spectroscopic instruments

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Ease of operation

If simple low-cost monitoring methods are used, then ease of operation is improved, but measurement precision deteriorates

Engineering Contradiction:
Improvesimplicity of detection methodVSAvoiddetection accuracy of catalyst fines
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The patent introduces chemical reagents as intermediaries that specifically react with catalyst fines to produce visible color changes, enabling simple visual detection while maintaining adequate precision for monitoring purposes

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The test method utilizes colorimetric changes resulting from chemical reactions between reagents and catalyst fines, providing a simple visual indicator that balances ease of operation with sufficient measurement precision

Inventive Principle:
Principle #32Color changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method provides a cost-effective and straightforward way to determine the presence of catalyst fines, allowing for timely action to prevent engine damage, with clear phase separation enabling visual assessment of fines presence without the need for expensive equipment.

Implementation Method 1

mixing the HFO sample with a diluent composition comprising a non-polar solvent and with an aqueous reagent composition to provide a test sample, wherein the aqueous reagent composition comprises at least one water soluble inorganic salt and at least one water soluble base; allowing phase separation to occur in the test sample to provide an aqueous phase and an organic phase

Methodology Applied
Scientific EffectPhase separation: Liquid-Liquid Extraction

Data Source

PatentEP3347439B1Methods for monitoring for the presence of catalyst fines in heavy fuel oils
Publication Date: 2019.07.10 PARKER HANNIFIN MFG LTD
  • EP3347439B1 patent drawingFigure 1
  • EP3347439B1 patent drawingFigure 2

AI summary

A method for monitoring for the presence of catalyst fines in a heavy fuel oil (HFO) is provided. The method comprises providing a sample of HFO; mixing the HFO sample with a diluent composition comprising a non-polar solvent and with an aqueous reagent composition to provide a test sample, wherein the aqueous reagent composition comprises at least one water soluble inorganic salt and at least one water soluble base; allowing phase separation to occur in the test sample to provide an aqueous phase and an organic phase; and inspecting the aqueous phase of the test sample for the presence of catalyst fines. Reagents and kits for use in such methods are also provided.