Catalytic Converter Oxygen Load Determination via NOx and Ammonia Signals

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Solution Overview

Problem

Existing methods for controlling the oxygen load of catalytic converters in internal combustion engines are not accurate for loads between 10% and 90%, leading to inefficiencies and potential nitrogen oxide emissions due to incomplete conversion.

Innovation Solution

A method using an exhaust gas sensor downstream of the catalytic converter to generate signals indicating nitrogen oxide and/or ammonia levels, allowing for precise determination of the oxygen load and adjusting the air-fuel mixture to maintain optimal oxygen levels, preventing nitrogen oxide slip.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a lambda probe is used to estimate the oxygen load of the catalytic converter, then the measurement is simple, but the measurement precision is insufficient for loads between 10% and 90%

Engineering Contradiction:
Improvemeasurement system complexityVSAvoidoxygen load measurement precision
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The patent uses nitrogen oxide and ammonia concentrations as intermediary parameters to indirectly determine oxygen load. Instead of directly measuring oxygen load with a complex sensor, the system measures nitrogen oxide and ammonia concentrations downstream of the catalytic converter, which serve as indicators of the oxygen storage capacity state. This intermediary approach resolves the contradiction by providing precise measurement without requiring complex direct oxygen load sensing.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the mechanical/chemical lambda probe measurement system with an analytical measurement system that detects nitrogen oxide and ammonia concentrations. This substitution enables more precise determination of oxygen load by measuring different chemical parameters (nitrogen oxide and ammonia levels) that correlate with oxygen storage capacity, particularly in the critical 10-90% load range where lambda probes fail.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Device complexity

If the catalytic converter oxygen load is not accurately controlled, then the control system is simple, but nitrogen oxide emissions increase due to incomplete conversion

Engineering Contradiction:
Improvecontrol system complexityVSAvoidnitrogen oxide emissions
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The patent implements a feedback control system where nitrogen oxide and ammonia concentrations measured downstream are used to determine oxygen load, which then feeds back to adjust the air-fuel mixture ratio. This closed-loop feedback ensures the catalytic converter maintains optimal oxygen storage capacity (40-60% load), preventing nitrogen oxide slip while managing emissions effectively. The feedback mechanism resolves the contradiction by automatically adjusting control complexity only when needed to maintain emission standards.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent employs dynamic control of the air-fuel mixture ratio based on real-time oxygen load assessment. Rather than using a fixed control strategy, the system dynamically adjusts the lambda value according to the current oxygen storage capacity state of the catalytic converter. This dynamic approach prevents nitrogen oxide emissions by adapting the control strategy to the actual converter state, resolving the contradiction between simple control and emission prevention.

Inventive Principle:
Principle #15Dynamics

3Productivity

If the oxygen load of the catalytic converter is maintained at 50%, then the conversion efficiency is optimized, but the control precision required is high

Engineering Contradiction:
Improvepollutant conversion efficiencyVSAvoidoxygen load control precision
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent uses nitrogen oxide and ammonia concentrations as intermediary indicators to precisely track oxygen load without requiring direct oxygen measurement. By measuring these intermediary parameters downstream, the system achieves the high control precision needed to maintain 50% oxygen load (40-60% range), which optimizes pollutant conversion efficiency. The intermediary measurement approach enables precise control that would be difficult to achieve with direct oxygen sensing.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs periodic switching between rich and lean air-fuel mixture operations to actively manage and assess the oxygen storage capacity of the catalytic converter. This periodic action allows the system to dynamically maintain the oxygen load within the optimal 40-60% range, achieving high conversion efficiency while using measurable changes in nitrogen oxide and ammonia concentrations to monitor and control the precise oxygen load state.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables reliable and accurate assessment of the catalytic converter's oxygen load, preventing nitrogen oxide emissions by adjusting the air-fuel mixture, thus maintaining efficient conversion of pollutants.

Implementation Method 1

generating at least one signal by means of the exhaust gas sensor (110) that indicates the proportion of nitrogen oxide and/or ammonia in the exhaust gas

Methodology Applied
Scientific EffectElectrical signal generation by exhaust gas sensor:

Implementation Method 2

Exhaust gas aftertreatment by a three-way catalytic converter converts carbon monoxide (CO), nitrogen oxides (NOx), and uncombusted hydrocarbons (HC) to carbon dioxide (CO2), nitrogen (N2), and water (H2O)

Methodology Applied
Scientific EffectCatalytic conversion: Catalysis

Implementation Method 3

control the oxygen load of the catalytic converter, especially of the three-way catalytic converter, in such a way that the catalytic converter is saturated/loaded with about 50% oxygen

Methodology Applied
Scientific EffectOxygen storage: Adsorption

Data Source

PatentUS11578636B2Method for determining the oxygen load of a catalytic converter of an internal combustion engine, and exhaust system of an internal combustion engine
Publication Date: 2023.02.14 VITESCO TECHNOLOGIES GMBH
  • US11578636B2 patent drawing
  • US11578636B2 patent drawing

AI summary

Various embodiments include a method of ascertaining the oxygen load of a catalytic converter disposed in an exhaust tract of an internal combustion engine with an exhaust gas sensor is disposed downstream of the catalytic converter comprising: generating a signal using the exhaust gas sensor indicating a proportion of nitrogen oxide and/or ammonia in the exhaust gas; and ascertaining the oxygen load of the catalytic converter at least partly on the basis of the signal from the exhaust gas sensor.