Catalyst Regeneration Halogen Retention via Moisture Removal

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Solution Overview

Problem

Existing catalyst regeneration processes face challenges in maintaining halogen content during catalyst regeneration due to moisture buildup in process streams, which can lead to halogen loss and reduced catalyst efficiency.

Innovation Solution

Incorporating a water-removing material, such as a stable membrane or beads, to selectively remove moisture from regeneration vent gas and reduction gas, ensuring a dry environment for halogen retention and recovery, thereby preventing halogen loss and improving catalyst regeneration yields.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a catalyst regeneration system processes vent gas through a burn zone to regenerate catalyst particles, then coke is removed from the catalyst, but moisture builds up in the process streams causing halogen loss from the catalyst

Engineering Contradiction:
Improvecatalyst regeneration efficiencyVSAvoidhalogen loss from catalyst
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent extracts and removes moisture from the process streams using a water removing material. The water removing material selectively removes water from the vent gas and reduction gas streams, separating the harmful moisture component from the beneficial process gases while maintaining halogen content for catalyst regeneration

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The water removing material acts as an intermediary component between the burn zone and the adsorption/desorption system. It mediates the process by removing moisture before gases enter subsequent zones, preventing halogen loss while allowing the regeneration process to continue efficiently

Inventive Principle:
Principle #24Intermediary (Mediator)

2Loss of substance

If water removing material is added to remove moisture from process streams, then halogen retention is improved, but device complexity increases

Engineering Contradiction:
Improvehalogen retentionVSAvoidregeneration system complexity
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

The water removing material utilizes porous material properties to selectively adsorb and remove moisture from the process streams. The porous structure provides high surface area for water interaction while maintaining permeability to other gases, achieving effective drying without complex mechanical systems

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The system employs composite material functionality where the water removing material combines properties of selective permeability and chemical stability in acidic environments. This allows a single material to perform multiple functions: water removal, halogen retention, and resistance to corrosive conditions

Inventive Principle:
Principle #40Composite materials

3Productivity

If moisture is not removed from reduction gas, then the system operation is simple, but catalyst reduction efficiency decreases

Engineering Contradiction:
Improvecatalyst reduction efficiencyVSAvoidgas drying system
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The water removing material performs preliminary drying of the reduction gas before it enters the reduction zone. By removing moisture in advance, the reduction process operates under optimal dry conditions, improving catalyst reduction efficiency without requiring complex post-processing systems

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of water-removing materials effectively reduces moisture in the catalyst regeneration system, enhancing halogen retention and recovery, leading to improved catalyst regeneration efficiency and increased yields by maintaining a dry environment for halogen-containing catalysts.

Implementation Method 1

a water removing material, such as a membrane, wherein water can be selectively rejected from the regeneration vent gas

Methodology Applied
Scientific EffectSelective permeation: Semipermeable Membrane

Implementation Method 2

The membrane is very stable in the highly acidic environment and highly selective to reacting with and removing water

Methodology Applied
Scientific EffectChemical reaction with water:

Implementation Method 3

an adsorption/desorption system to recover the chlorine

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

an adsorption/desorption system to recover the chlorine

Methodology Applied
Scientific EffectDesorption: Desorption

Data Source

PatentUS9868118B2Process for regenerating catalyst particles
Publication Date: 2018.01.16 UOP LLC
  • US9868118B2 patent drawing
  • US9868118B2 patent drawing
  • US9868118B2 patent drawing

AI summary

A process for regenerating catalyst particles is disclosed. The process includes the steps: (a) withdrawing a regeneration zone effluent comprising halogen from a regeneration zone, wherein the regeneration zone contains catalyst particles comprising halogen; (b) contacting a first portion of the regeneration zone effluent with adsorbent in a first adsorption zone, removing halogen from the first portion of the regeneration zone effluent, and withdrawing from the first adsorption zone a first adsorption zone effluent; (c) contacting the first adsorption zone effluent with a water removing material to create a first water-depleted stream; and (d) passing the first water-depleted stream to the regeneration zone. Other embodiments include different orders of the steps.