Catalyst Slurry Mixing with Multi-Blade Impeller

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Solution Overview

Problem

The challenge in polymerization reactors is maintaining consistent catalyst concentration to control reactor conditions and polyolefin properties, as variations in catalyst concentration lead to uneven density and molecular weight distribution in polyolefin particles.

Innovation Solution

A catalyst slurry preparation system with a rotatable impeller system featuring a hub with at least three blades is used to mix a catalyst slurry comprising a solid particulate catalyst and a carrier liquid, ensuring homogeneous mixing and consistent catalyst concentration by reducing settling and improving mixing efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a simple mixing system is used, then device complexity is reduced, but mixing efficiency and homogeneity of catalyst slurry deteriorate

Engineering Contradiction:
Improvemixing system complexityVSAvoidcatalyst concentration uniformity
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The mixing system is divided into multiple mixing vessels arranged in series, with each vessel performing a specific mixing function. The catalyst slurry passes through multiple stages of mixing, allowing progressive homogenization without requiring an overly complex single-vessel system. This segmentation achieves uniform catalyst distribution while keeping individual vessel designs relatively simple.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a vertical dimension to the mixing process by using multiple mixing vessels stacked or arranged in sequence, rather than relying solely on horizontal mixing within a single vessel. This multi-stage approach in the vertical dimension enhances mixing efficiency and catalyst concentration uniformity without significantly increasing the complexity of individual mixing components.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Productivity

If catalyst concentration is increased to improve productivity, then polyolefin production rate increases, but reactor temperature control and polyolefin property consistency deteriorate

Engineering Contradiction:
Improvepolyolefin production rateVSAvoidreactor temperature control
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The catalyst slurry is prepared and pre-mixed in the mixing vessels before being introduced to the polymerization reactor. This preliminary mixing action ensures that the catalyst is uniformly distributed and at the desired concentration, allowing the reactor to maintain better temperature control and product consistency even when operating at high productivity levels. The pre-mixing prevents localized concentration spikes that would otherwise cause temperature runaway.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The mixing vessels act as intermediaries between catalyst storage and the polymerization reactor. They buffer and regulate the catalyst delivery, ensuring steady-state concentration in the reactor feed. This intermediary function allows the system to maintain reliable temperature control and polyolefin property consistency while supporting high productivity by decoupling the catalyst storage system from the reactor operation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If catalyst slurry mixing is improved to maintain consistent concentration, then polyolefin property control improves, but mixing time and energy consumption increase

Engineering Contradiction:
Improvepolyolefin property consistencyVSAvoidmixing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The mixing vessels are designed for continuous operation, with catalyst slurry flowing continuously through multiple mixing stages. This continuous mixing action maintains consistent catalyst concentration without requiring prolonged stopping or extensive mixing time. The multi-vessel series arrangement allows overlapping mixing operations, where while one vessel is being filled, another is being mixed, thereby reducing overall mixing time while maintaining polyolefin property consistency.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The system optimizes mixing parameters such as impeller speed, residence time in each vessel, and flow rates to achieve effective mixing in minimal time. By carefully controlling these parameters across the multiple vessels, the system maintains consistent catalyst concentration and polyolefin properties without excessive mixing time or energy consumption. The parameter optimization allows rapid mixing while preserving product quality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system maintains consistent catalyst concentration throughout the polymerization process, reducing reactor temperature fluctuations and enhancing the homogeneity of the catalyst slurry, thereby improving the control of polyolefin properties.

Implementation Method 1

a rotatable impeller system connected to the mixing vessel... configured to mix the catalyst slurry in the mixing vessel

Methodology Applied
Scientific EffectMechanical mixing: Stirring

Implementation Method 2

the first hub comprises at least three blades... reducing settling and improving mixing efficiency

Methodology Applied
Scientific EffectTurbulence: Turbulence

Data Source

PatentUS12115506B2Catalyst slurry mixing process and system
Publication Date: 2024.10.15 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • US12115506B2 patent drawing
  • US12115506B2 patent drawing
  • US12115506B2 patent drawing

AI summary

Disclosed are a process and system for preparing a catalyst slurry. The process can include preparing a catalyst slurry comprising a solid particulate catalyst and a carrier liquid in a catalyst slurry preparation system. The catalyst slurry preparation system can include a mixing vessel, a rotatable impeller system connected to the mixing vessel, and a motor connected to the rotatable impeller system. The rotatable impeller system can include an agitator shaft and a hub connected to the agitator shaft. The hub and at least a portion of the agitator shaft are positioned within the mixing vessel along a longitudinal axis of the mixing vessel, and the hub has at least three blades.