Catalytic Enamel Composition for Fast Oven Cleaning

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Solution Overview

Problem

Conventional enamel compositions for cooking appliances require lengthy high-temperature heating and soaking processes, leading to high energy consumption and compromised durability, while also struggling with effective removal of oil and sugar contaminants.

Innovation Solution

An enamel composition comprising 15-50 wt% SiO2, 1-10 wt% B2O3, 10-20 wt% alkali metal oxides, 1-5 wt% NaF, and 20-50 wt% metal oxides like TiO2, MoO3, Bi2O3, CeO2, MnO2, or Fe2O3, which is applied in a novel composition ratio to facilitate efficient cleaning at reduced temperatures and without water soaking, using a buffer layer on a base steel sheet to enhance durability and chemical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional enamel compositions are used for pyrolysis cleaning, then cleaning function is achieved, but cleaning time is excessively long (about four hours) and energy consumption is high

Engineering Contradiction:
Improvecleaning speedVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent modifies the chemical composition parameters of the enamel coating by incorporating specific metal oxides (TiO2, MoO3, Bi2O3, CeO2, MnO2, Fe2O3) in optimized ratios, along with SiO2, B2O3, and alkali metal oxides. This compositional parameter change enables the enamel to catalyze decomposition of organic contaminants at lower temperatures (400-450°C) and shorter durations (10-30 minutes), dramatically reducing both cleaning time and energy consumption compared to conventional enamels requiring 4 hours at high temperature

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite enamel material combining multiple metal oxides with glass formers (SiO2, B2O3) and network modifiers (alkali metal oxides). This composite structure provides synergistic effects where metal oxides act as catalysts for contaminant decomposition while the glass matrix maintains coating integrity, achieving both rapid cleaning performance and durability at reduced energy input

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional enamel compositions are used, then cleaning is possible, but the process requires soaking in water for extended periods to remove oil contaminants

Engineering Contradiction:
Improvecleaning easeVSAvoidcleaning process complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent enables the enamel coating to perform self-cleaning through catalytic decomposition. The metal oxide components actively catalyze the breakdown of organic contaminants (oils, fats, food residues) into volatile substances that evaporate at cleaning temperatures, eliminating the need for water soaking and manual scrubbing. The coating serves its own cleaning function, transforming from a passive protective layer to an active self-cleaning surface

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces the mechanical cleaning approach (water soaking and manual scrubbing) with a chemical-catalytic mechanism. Instead of relying on mechanical force and prolonged water contact to remove contaminants, the enamel's metal oxide components catalyze chemical decomposition of organic matter, converting it into removable ash and gas products that can be easily wiped away, thereby simplifying the cleaning process

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If other enamel compositions are used, then cleaning may be performed, but durability is degraded at high temperatures

Engineering Contradiction:
ImprovedurabilityVSAvoidheat resistance
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent employs a composite enamel system where metal oxides (TiO2, MoO3, Bi2O3, CeO2, MnO2, Fe2O3) are embedded within a stable glass matrix composed of SiO2, B2O3, and alkali metal oxides. This composite structure provides thermal stability through the glass matrix while the metal oxide particles maintain catalytic activity at elevated temperatures. The synergistic combination ensures the coating withstands repeated heating cycles (400-450°C) without degradation, cracking, or loss of cleaning efficacy

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent assigns different functional properties to different components within the enamel coating. The glass formers (SiO2, B2O3) provide structural integrity and thermal stability, while the metal oxides localized within the matrix provide catalytic activity for contaminant decomposition. This spatial distribution of specialized functions allows the coating to simultaneously maintain durability at high temperatures while delivering effective self-cleaning performance

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The enamel composition significantly reduces cleaning time, saves energy, and maintains excellent durability and chemical resistance, enabling efficient removal of contaminants like oils and sugars at room temperature without water soaking, thus improving hygiene and reducing operational costs.

Implementation Method 1

The enamel composition including components, such as phosphorus pentoxide (P2O5), silicon dioxide (SiO2), and boron oxide (B2O3) may be used with pyrolysis methods

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

pyrolysis methods for burning contaminants at high temperatures to ashes may be used to easily clean the inner wall of the cavity

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Data Source

PatentUS12006257B2Enamel composition, method for preparing enamel composition, and cooking appliance
Publication Date: 2024.06.11 LG ELECTRONICS INC
  • US12006257B2 patent drawing
  • US12006257B2 patent drawing
  • US12006257B2 patent drawing

AI summary

An enamel composition, a method for preparing an enamel composition, and a cooking appliance are provided. The enamel composition may include 15 to 50 wt % of silicon dioxide (SiO2); 1 to 10 wt % of boron oxide (B2O3); 10 to 20 wt % of at least one of lithium oxide (Li2O), sodium oxide (Na2O), or potassium oxide (K2O); 1 to 5 wt % of sodium fluoride (NaF); 1 to 10 wt % of zinc oxide (ZnO); and 20 to 50 wt % of at least one of titanium dioxide (TiO2), molybdenum oxide (MoO3), bismuth oxide (Bi2O3), cerium dioxide (CeO2), manganese dioxide (MnO2), or Iron oxide (Fe2O3), which provides an enamel composition with a reduced cleaning time, and facilitates cleaning without soaking in water.